Pounce® 384 ec insecticide

MATERIAL SAFETY DATA SHEET
POUNCE® 384 EC INSECTICIDE
MSDS Ref. No.: 52645-53-1-43
Date Approved: 06/05/2007
Revision No.: 1
This document has been prepared to meet the requirements of the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200; the EC Directive, 2001/58/EC; and, the Canada.s Workplace Hazardous Materials Information System (WHMIS). The information contained herein is for the concentrate as packaged, unless otherwise noted. 1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME:
PRODUCT CODE:
ACTIVE INGREDIENT(S):
CHEMICAL FAMILY:
MOLECULAR FORMULA:
SYNONYMS:
FMC 33297; (3-Phenoxyphenyl)methyl(+/-) cis-trans-3-(2,2- dichloroethenyl)-2,2-dimethylcyclopropanecarboxylate; IUPAC: 3-phenoxybenzyl (1RS)-cis-trans-3-(2,2-dichlorovinyl)-2,2- dimethylcyclopropanecarboxylate MANUFACTURER
EMERGENCY TELEPHONE NUMBERS
(800) 331-3148 (FMC - U.S.A. & Canada) For leak, fire, spill, or accident emergencies, call: [email protected] (Email - General Information) (800) 424-9300 (CHEMTREC - U.S.A. & Canada) (703) 527-3887 (CHEMTREC - All Other Countries) 2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
• Amber liquid with an aromatic solvent odor. • Moderately combustible. May support combustion if heated above the product's flash point (see Section 9, "Physical and Chemical Properties" below). • Thermal decomposition and burning may form toxic by-products. • For large exposures or fire, wear personal protective equipment. • Highly toxic to fish and aquatic organisms. Keep out of drains and water courses. • Moderately irritating to the skin and eyes. POUNCE® 384 EC INSECTICIDE (52645-53-1-43) POTENTIAL HEALTH EFFECTS: Effects from overexposure result from either
swallowing, or coming into contact with the skin or eyes. Symptoms of overexposure include diarrhea,
salivation, tremors, convulsions, hyperactivity and hypersensitivity. Contact with this product has rarely
produced skin sensations such as numbing, burning and tingling. These sensations are reversible and
usually subside within 12 hours.
MEDICAL CONDITIONS AGGRAVATED: None presently known.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name
R20/22-43-50/53; S2-13-24-36/37/39-60-61 R10-37-51/53-65-66-67; S23-24-43A-57-60-62 R10-22-37/38-41-67; S2-7/9-13-26-37/39-46 4. FIRST AID MEASURES
EYES: Flush with water for at least 15 minutes. If irritation occurs and persists, contact a medical
doctor.
SKIN: Remove contaminated clothing and thoroughly wash with soap and water. If irritation occurs and
persists, contact a medical doctor.
INGESTION: Do not induce vomiting and do not give liquids of any kind to the person. Never give
anything by mouth to an unconscious person. See a medical doctor immediately.
POUNCE® 384 EC INSECTICIDE (52645-53-1-43) INHALATION: Remove to fresh air. If breathing difficulty or discomfort occurs and persists,
contact a medical doctor.
NOTES TO MEDICAL DOCTOR: This product has low oral, dermal and inhalation
toxicity. It is moderately irritating to the skin and eyes. Reversible skin sensations (paresthesia) may occur
and ordinary skin salves have been found useful in reducing discomfort. Contains aromatic hydrocarbons
that may produce a severe pneumonitis if aspirated during vomiting. Consideration should be given to
gastric lavage with an endotracheal tube in place. Treatment is otherwise controlled removal of exposure
followed by symptomatic and supportive care.
5. FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: Foam, CO2 or dry chemical. Soft stream water fog only if
necessary. Contain all runoff.
FIRE / EXPLOSION HAZARDS: Moderately combustible. When heated above the flash
point, this material releases vapors which, when mixed with air, can burn or be explosive.
FIRE FIGHTING PROCEDURES: Isolate fire area. Evacuate downwind. Wear full
protective clothing and self-contained breathing apparatus. Do not breathe smoke, gases or vapors
generated.
FLAMMABLE LIMITS: Not available
6. ACCIDENTAL RELEASE MEASURES
RELEASE NOTES: Isolate and post spill area. Wear protective clothing and personal protective
equipment as prescribed in Section 8, "Exposure Controls/Personal Protection". Keep unprotected persons
and animals out of the area.
Keep material out of lakes, streams, ponds and sewer drains. Dike to confine spill and absorb with a non-combustible absorbent such as clay, sand or soil. Vacuum, shovel or pump waste into a drum and label contents for disposal. To clean and neutralize contaminated area, scrub area with a solution of detergent (e.g. commercial product such as SuperSoap™, Tide®, Spic and Span®, or other high pH detergent) and water. Let solution sit for 5 minutes. Use a stiff brush to scrub affected area. Repeat if necessary to remove visible staining. Additional decontamination can be made by applying bleach (Clorox® or equivalent) to affected area. Absorb wash-liquid as noted above, remove visibly contaminated soil and place into recovery / disposal container (plastic, open-top steel drum or equivalent). Place all clean-up material in a container, seal and dispose of in accordance with the method outlined in Section 13 "Disposal Considerations" below. For further information on spill clean-up, waste disposal, or return of salvaged product, call the FMC Emergency Hotline number listed in Section 1 "Product and Company Identification" above. POUNCE® 384 EC INSECTICIDE (52645-53-1-43) 7. HANDLING AND STORAGE
HANDLING AND STORAGE: Store in a cool, dry, well-ventilated place. Do not use or
store near heat, open flame or hot surfaces. Store in original containers only. Keep out of reach of children
and animals. Do not contaminate other pesticides, fertilizers, water, food or feed by storage or disposal.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE LIMITS
Chemical Name
Supplier
20 ppm (TWA) (ceiling) 100 ppm (TWA) (ceiling)
ENGINEERING CONTROLS: Use local exhaust at all process locations where vapor or
mist may be emitted. Ventilate all transport vehicles prior to unloading.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: For splash, mist or spray exposure, wear chemical protective goggles
or a face shield.
RESPIRATORY: For splash, mist or spray exposures wear, as a minimum, a properly
fitted half-face or full-face air-purifying respirator which is approved for pesticides (U.S.
NIOSH/MSHA, EU CEN or comparable certification organization). Respirator use and selection
must be based on airborne concentrations.
PROTECTIVE CLOTHING: Depending upon concentrations encountered, wear
coveralls or long-sleeved uniform and head covering. For larger exposures as in the case of spills,
wear full body cover barrier suit, such as a PVC suit. Leather items - such as shoes, belts and
POUNCE® 384 EC INSECTICIDE (52645-53-1-43) watchbands - that become contaminated should be removed and destroyed. Launder all work clothing before reuse (separately from household laundry). GLOVES: Wear chemical protective gloves made of materials such as nitrile, neoprene or
Viton® brand. Thoroughly wash the outside of gloves with soap and water prior to removal.
Inspect regularly for leaks.

WORK HYGIENIC PRACTICES: Clean water should be available for washing in case of
eye or skin contamination. Wash skin prior to eating, drinking, chewing gum, or using tobacco. Shower at
the end of the workday.

COMMENTS:
CANADIAN OCCUPATIONAL EXPOSURE LIMITS (OELs)
Xylene:
Alberta: 150 ppm, 651 mg/m³ (STEL); 100 ppm, 434 mg/m³ (TWA)
British Columbia: 150 ppm (STEL); 100 ppm (TWA)
Manitoba: 150 ppm, 655 mg/m³ (STEL); 100 ppm, 435 mg/m³ (TWA)
New Brunswick: 150 ppm, 651 mg/m³ (STEL); 100 ppm, 434 mg/m³ (TWA)
Northwest Territories: 150 ppm, 652 mg/m³ (SEL); 100 ppm, 434 mg/m³ (TWA)
Nova Scotia: 150 ppm (STEL); 100 ppm (TWA)
Nunavut: 150 ppm, 652 mg/m³ (STEL); 100 ppm, 434 mg/m³ (TWA)
Ontario: 150 ppm, 650 mg/m³ (STEV); 100 ppm, 435 mg/m³ (TWAEV)
Quebec: 150 ppm, 651 mg/m³ (STEV); 100 ppm, 434 mg/m³ (TWAEV)
Saskatchewan: 150 ppm, 651 mg/m³ (STEL); 100 ppm, 434 mg/m³ (TWA)
Yukon: 150 ppm, 650 mg/m³ (STEL); 100 ppm, 435 mg/m³ (TWA)
Cumene:
Alberta: 50 ppm, 246 mg/m³ (TWA)
British Columbia: 75 ppm (STEL); 25 ppm (TWA)
Manitoba: 50 ppm, 245 mg/m³ (TWA)
New Brunswick: 50 ppm, 246 mg/m³ (TWA)
Northwest Territories: 75 ppm, 370 mg/m³ (STEL); 50 ppm, 245 mg/m³ (TWA)
Nova Scotia: 50 ppm (TWA)
Nunavut: 75 ppm, 370 mg/m³ (STEL); 50 ppm, 245 mg/m³ (TWA)
Ontario: 50 ppm, 245 mg/m³ (TWAEV)
Quebec: 50 ppm, 246 mg/m³ (TWAEV)
Saskatchewan: 74 ppm, 365 mg/m³ (STEL); 50 ppm, 245 mg/m³ (TWA)
Yukon: 75 ppm, 365 mg/m³ (STEL); 150 ppm, 245 mg/m³ (TWA)
1-butanol
Alberta: 50 ppm, 246 mg/m³ (TWA)
British Columbia: 30 ppm (Ceiling); 15 ppm (TWA)
Manitoba: 50 ppm, 245 mg/m³ (TWA)
New Brunswick: 50 ppm, 246 mg/m³ (TWA)
Nova Scotia: 20 ppm (TWA)
Nunavut: 50 ppm, 152 mg/m³ (Ceiling)
Ontario: 20 ppm (STEV)
Saskatchewan: 50 ppm, 152 mg/m³ (Ceiling)
Yukon: 50 ppm, 150 mg/m³ (Ceiling)
POUNCE® 384 EC INSECTICIDE (52645-53-1-43) Ethylbenzene: Alberta: 125 ppm, 543 mg/m³ (STEL); 100 ppm, 434 mg/m³ (TWA) British Columbia: 125 ppm (STEL); 100 ppm (TWA) Manitoba: 125 ppm, 54 mg/m³ (STEL); 100 ppm, 435 mg/m³ (TWA) New Brunswick: 125 ppm, 543 mg/m³ (STEL); 100 ppm, 434 mg/m³ (TWA) Northwest Territories: 125 ppm, 542 mg/m³ (STEL); 100 ppm, 434 mg/m³ (TWA) Nova Scotia: 125 ppm (STEL); 100 ppm (TWA) Nunavut: 125 ppm, 542 mg/m³ (STEL); 100 ppm, 434 mg/m³ (TWA) Ontario: 125 ppm, 540 mg/m³ (STEV); 100 ppm, 435 mg/m³ (TWAEV) Quebec: 125 ppm, 543 mg/m³ (STEV); 100 ppm, 434 mg/m³ (TWAEV) Saskatchewan: 125 ppm, 543 mg/m³ (STEL); 100 ppm, 435 mg/m³ (TWA) Yukon: 125 ppm, 545 mg/m³ (STEL); 100 ppm, 435 mg/m³ (TWA) 9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE:
AUTOIGNITION TEMPERATURE:
BOILING POINT:
COEFFICIENT OF OIL / WATER:
DENSITY / WEIGHT PER VOLUME:
EVAPORATION RATE:
FLASH POINT:
MELTING POINT:
MOLECULAR WEIGHT:
SOLUBILITY IN WATER:
SPECIFIC GRAVITY:
VAPOR DENSITY:
VAPOR PRESSURE:
10. STABILITY AND REACTIVITY
CONDITIONS TO AVOID:
STABILITY:
POLYMERIZATION:
POUNCE® 384 EC INSECTICIDE (52645-53-1-43) HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide and/or carbon dioxide. Chlorine
11. TOXICOLOGICAL INFORMATION
EYE EFFECTS: Moderately irritating
SKIN EFFECTS: Moderately irritating
DERMAL LD50: > 2,000 mg/kg (rabbit)
ORAL LD50: 1,030 mg/kg (rat)
INHALATION LC50: > 25.7 mg/l (4 h) (rat)
ACUTE EFFECTS FROM OVEREXPOSURE: This product has low oral, dermal
and inhalation toxicity. It is moderately irritating to the skin and eyes. Experience to date indicates that
contact with this product has rarely produced skin sensations such as numbing, burning or tingling. These
sensations are reversible and usually subside within 12 hours. Large, toxic doses administered to laboratory
animals have produced symptoms such as diarrhea, salivation, tremors and intermittent convulsions.
Overexposure to animals, via inhalation, has also produced hyperactivity and hypersensitivity. Inhalation of
aromatic hydrocarbon vapors may cause dizziness, disturbances in vision, drowsiness, respiratory irritation,
and eye, skin and mucous membrane irritation. Vomiting after ingestion of this product may cause
aspiration of aromatic hydrocarbons into the lungs, which may result in fatal pulmonary edema.
CHRONIC EFFECTS FROM OVEREXPOSURE: No data available for the
formulation. In studies with laboratory animals, permethrin did not cause reproductive toxicity or
teratogenicity. Analysis of chronic feeding studies in both mice and rats with permethrin resulted in the
conclusion that permethrin's potential for induction of oncogenicity in experimental animals is low and that
the likelihood of oncogenic effects in humans is nonexistent or extremely low. Long-term feeding studies in
animals resulted in increased liver and kidney weights, induction of the liver microsomal drug metabolizing
enzyme system and histopathological changes in the lungs and liver. An overall absence of genotoxicity has
been demonstrated in mutagenicity testing with permethrin. Chronic exposure to aromatic hydrocarbons
may cause headaches, dizziness, loss of sensations or feelings (such as numbness), and liver and kidney
damage. Inhalation of xylene vapors at high doses has also resulted in an increased incidence of
malformations and decreases in fetal weight in laboratory animals. Damage from xylene may be potentiated
by alcohol. Under the conditions of 2-year inhalation studies, conducted by the National Toxicology
Program (NTP), there was clear evidence of carcinogenic activity of ethylbenzene in male rats based on
increased incidences of renal tubule neoplasms. The incidences of testicular adenoma were also increased.
There was some evidence of carcinogenic activity in female rats based on increased incidences of renal
tubule adenomas. There was some evidence of carcinogenic activity in male mice based on increased
incidences of alveolar/bronchiolar neoplasm. There was some evidence of carcinogenic activity in female
mice based on increased incidences of hepatocellular neoplasms. Studies conducted by the International
Agency for Research on Cancer (IARC) showed that there is inadequate evidence in humans for the
carcinogenicity of ethylbenzene and that there is sufficient evidence in experimental animals; therefore, the
overall evaluation shows that ethylbenzene is possibly carcinogenic to humans (Group 2B).
POUNCE® 384 EC INSECTICIDE (52645-53-1-43) CARCINOGENICITY:
Chemical Name
12. ECOLOGICAL INFORMATION
Unless otherwise indicated, the data presented below are for the active ingredient.
ENVIRONMENTAL DATA: Permethrin is stable at a wide range of pH values. Permethrin
has a moderate rate of degradation in soil and the half-life is related to the soil type, microbial population, concentration in the soil and the aerobic condition of the soil. Because of its high affinity for organic matter (Koc = 86,000), there is little potential for movement in soil or entry into ground water. Permethrin has a Log Pow of 6.1, but because of the ease with which biological systems degrade the molecule, the potential for bioconcentration and accumulation in the environment is low (BCF = 500).
ECOTOXICOLOGICAL INFORMATION: Permethrin is highly toxic to fish (LC50 =
0.5 µg/L to 315 µg/L) and aquatic arthropods (LC50 = 0.02 µg/L to 7.6 µg/L). Marine species are often more sensitive than the freshwater species. Bacteria, algae, mollusks and amphibians are much more tolerant of permethrin than the fish and arthropods. Care should be taken to avoid contamination of the aquatic environment. Permethrin is slightly toxic to birds and oral LD50 values are greater than 3600 mg/kg. Longer dietary studies showed that concentrations of up to 500 ppm in the diet had no effect on bird reproduction. 13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Open dumping or burning of this material or its packaging is prohibited.
If spilled material cannot be disposed of by use according to label instructions, an acceptable method of
disposal is to incinerate in accordance with local, state and national environmental laws, rules, standards
and regulations. However, because acceptable methods of disposal may vary by location and regulatory
requirements may change, the appropriate agencies should be contacted prior to disposal.
EMPTY CONTAINER: Non-returnable containers that held this material should be cleaned,
prior to disposal, by triple rinsing. Containers which held this material may be cleaned by being triple-
rinsed, and recycled, with the rinsate being incinerated. Do not cut or weld metal containers. Vapors that
form may create an explosion hazard.
14. TRANSPORT INFORMATION

U.S. DEPARTMENT OF TRANSPORTATION (DOT)
PACKAGING TYPE:
POUNCE® 384 EC INSECTICIDE (52645-53-1-43) ADDITIONAL INFORMATION:
This product has been reclassified from Flammable Liquid to Combustible Liquid in accordance with the provisions at 49 CFR § 173.150(f)(1). As a Combustible Liquid, this material is not subject to the hazardous materials regulations when transported within the USA in non-bulk packages per 49 CFR § 173.150(f)(2). PACKAGING TYPE:
PROPER SHIPPING NAME:
TECHNICAL NAME(S):
PRIMARY HAZARD CLASS / DIVISION:
UN/NA NUMBER:
PACKING GROUP:
MARINE POLLUTANT:
PLACARD(S):
MARKING(S):
REPORTABLE QUANTITY (RQ):
ADDITIONAL INFORMATION:
Xylene is in an "RQ" quantity when this material meets or exceeds 5,000 pounds (599 gallons) per package.
INTERNATIONAL MARITIME DANGEROUS GOODS (IMDG)

PACKAGING TYPE:
PROPER SHIPPING NAME:
TECHNICAL NAME(S):
PRIMARY HAZARD CLASS / DIVISION:
UN/NA NUMBER:
PACKING GROUP:
MARINE POLLUTANT:
LABEL(S):
PLACARD(S):
MARKING(S):
Flammable liquid, n.o.s. (aromatic hydrocarbons, permethrin), UN1993 + Marine Pollutant ADDITIONAL INFORMATION:
POUNCE® 384 EC INSECTICIDE (52645-53-1-43)

ADR - EUROPEAN AGREEMENT CONCERNING THE
INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD

PACKAGING TYPE:
PROPER SHIPPING NAME:
TECHNICAL NAME(S):
PRIMARY HAZARD CLASS / DIVISION:
CLASSIFICATION CODE:
UN/NA NUMBER:
PACKING GROUP:
HAZARD IDENTIFICATION NUMBER:
MARINE POLLUTANT:
LABEL(S):
PLACARD(S):
MARKING(S):


INTERNATIONAL CIVIL AVIATION ORGANIZATION (ICAO) /
INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA)

PACKAGING TYPE:
PROPER SHIPPING NAME:
TECHNICAL NAME(S):
PRIMARY HAZARD CLASS / DIVISION:
UN/NA NUMBER:
PACKING GROUP:
LABEL(S):
LIMITED QUANTITY:
LIMITED QUANTITY: PASSENGER / CARGO:
LIMITED QUANTITY: CARGO:
ADDITIONAL INFORMATION:
Depending on requirements of the country of origin or destination, the addition of "Marine Pollutants" to the Marks and shipping paper description may be appropriate. POUNCE® 384 EC INSECTICIDE (52645-53-1-43) Marks: Flammable liquid, n.o.s. (aromatic hydrocarbons), UN1993
OTHER INFORMATION:
HARMONIZED SYSTEM
Import to the U.S.A.: 3808.91.2500
Export from the U.S.A.: 3808.91.0000
CANADIAN TRANSPORT (TDG):
PACKAGE TYPE:
Small and large means of containment
ADDITIONAL INFORMATION:
This material is not regulated when trasnported by road in Canada.
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355, APPENDIX A):

SECTION 311 HAZARD CATEGORIES (40 CFR 370):

SECTION 312 THRESHOLD PLANNING QUANTITY (40 CFR 370):
The Threshold Planning Quantity (TPQ) for this product, if treated as a mixture, is 10,000 lbs; however, this product contains the following ingredients with a TPQ of less than 10,000 lbs.: None
SECTION 313 REPORTABLE INGREDIENTS (40 CFR 372):
This product contains the following ingredients subject to Section 313 reporting requirements: Permethrin, 1,2,4-trimethylbenzene, Xylene (mixed isomers), Cumene, 1-butanol, Ethylbenzene CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND
LIABILITY ACT)
CERCLA DESIGNATION & REPORTABLE QUANTITIES (RQ) (40 CFR 302.4):
POUNCE® 384 EC INSECTICIDE (52645-53-1-43) FEDERAL INSECTICIDE FUNGICIDE RODENTICIDE ACT
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM):
Hazard Classification / Division: B3 Ingredient Disclosure List: Hazard Classification / Division: B2, D.2.A, D.2.B. Ingredient Disclosure List: Hazard Classification / Division: B2 Domestic Substance List: Hazard Classification / Division: B2, D2B Ingredient Disclosure List: Hazard Classification / Division: B2, D.2.A, D.2.B. Ingredient Disclosure List: INTERNATIONAL LISTINGS
CANADIAN 2005 / 2006 NATIONAL POLLUTANT RELEASE INVENTORY (NPRI): Aromatic hydrocarbons: Part 5 Substance 1,2,4-trimethylbenzene: Part 1, Group 1 Substance; Part 5 Substance Xylene: Part 1 Group 1 Substance, Part 5 Substance Cumene: Part 1 Group 1 Substance 1-butanol: Part 1 Group 1 Substance Ethylbenzene: Part 1 Group 1 Substance
COMMENTS:

This product has been classified in accordance with the hazard criteria of the Controlled Products
Regulations, and the MSDS contains all the information required by the Controlled Products
Regulations.

16. OTHER INFORMATION
POUNCE® 384 EC INSECTICIDE (52645-53-1-43) REVISION SUMMARY:
New MSDS.
Pounce and FMC - Trademarks of FMC Corporation
Viton - E.I. du Pont de Nemours & Co. Trademark
SuperSoap - Trademark of Weba Technologies, Inc.; Tide - Trademark of Proctor and Gamble; Spic and
Span: Trademark of The Spic and Span Company; Clorox - Trademark of The Clorox Company
2007 FMC Corporation. All Rights Reserved.
FMC Corporation believes that the information and recommendations contained herein (including data and
statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR
PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED
OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information
provided herein relates only to the specific product designated and may not be applicable where such
product is used in combination with any other materials or in any process. It is a violation of Federal law to
use this product in a manner inconsistent with its labeling. Further, since the conditions and methods of use
are beyond the control of FMC Corporation, FMC Corporation expressly disclaims any and all liability as
to any results obtained or arising from any use of the product or reliance on such information.

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