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MATERIAL SAFETY DATA SHEET Finished Product.
SECTION 1 – CHEMICAL SUBSTANCE/PRODUCT AND COMPANY
IDENTIFICATION
Finished Product Name: Natural Instincts for Men
This product is sold as a three component kit: Natural Instincts Colorant, Natural Instincts
Developing Lotion & Natural Instincts Color Conditioning Treatment.
• Natural Instincts Colorant Shades M3 (95171528), M5 (95171524), M7 (95171529), M9
(95171525), M11 (95171521), M13 (95171527), M15 (95171523), M17 (95171523), M19
(95171531)

• Natural Instincts Developing Lotion (95171532)
• Natural Instincts Color Conditioning Treatment (95577702)
Company Identification:
Clairol, A Division of The Procter & Gamble Company, Stamford, CT 06922
Contact: Consumer Relations at 1-800-252-4765
In case of medical emergencies, please contact your local poison control center.
Transportation emergency (24 hour), contact:
CHEMTREC - Phone # 1-800-424-9300 (U.S. and Canada) or 1-703-527-3887 (for calls originating elsewhere).
DATE: August 2007
SECTION 2 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
This is a personal care or cosmetic product that is safe for consumers and other users under
intended and reasonably foreseeable use. Additional information on toxicological endpoints is
available from the supplier upon request.
POTENTIAL HEALTH EFFECTS:
Eye:
Contact may cause mild to moderate transient irritation. Redness and/or stinging may occur.

Skin:
May cause irritation or sensitization in sensitive individuals. Depending on the nature of any
reaction experienced, a similar reaction may occur on subsequent uses of hair color products.

Inhalation:
May cause mild, transient respiratory irritation. Avoid prolonged contact to concentrated
vapors.

Ingestion:
Product used as intended is not expected to cause gastrointestinal irritation. Accidental ingestion
of undiluted product may cause mild gastrointestinal irritation with nausea, vomiting and
diarrhea.
SECTION 3 - COMPOSITION AND INGREDIENTS
The complete ingredient list for the finished product(s) is as follows:
Natural Instincts Colorant: Shade M3
Water, Hexylene Glycol, Ethanolamine, Propylene Glycol, Soytrimonium Chloride,
Trisodium Ethylenediamine Disuccinate, Ethoxydiglycol, Oleth-5, C11-15 Pareth-9,
Simmondsia Chinensis (JOJOBA) Seed Extract, Panax Ginseng Root Extract, Aloe Barbadensis
Flower Extract, Anthemis Nobilis Flower Extract, Hydrolyzed Wheat Protein, Hydrolyzed Silk,
Fragrance, Polysorbate 20, P-Phenylenediamine, Oleth-2, Dilinoleic Acid, Cocamidopropyl
Betaine, Oleic Acid, Resorcinol, Erythorbic Acid, Sodium Sulfite, Oleamide MIPA, C12-15
Pareth-3, N,N-Bis (2-Hydroxyethyl)-P-Phenylenediamine Sulfate, Tocopheryl Acetate, Oleth-
10, Panthenol, EDTA, M-Aminophenol, 1-Naphthol, P-Aminophenol

Natural Instincts Colorant: Shade M5
Water, Hexylene Glycol, Ethanolamine, Propylene Glycol, Soytrimonium Chloride, Trisodium
Ethylenediamine Disuccinate, Ethoxydiglycol, Oleth-5, C11-15 Pareth-9, Simmondsia Chinensis
( JOJOBA) Seed Extract, Panax Ginseng Root Extract, Aloe Barbadensis Flower Extract,
Anthemis Nobilis Flower Extract, Hydrolyzed Wheat Protein, Hydrolyzed Silk, Fragrance,
Polysorbate 20, P-Phenylenediamine, Oleth-2, Dilinoleic Acid, Cocamidopropyl Betaine, Oleic
Acid, Resorcinol, Erythorbic Acid, Sodium Sulfite, Oleamide MIPA, C12-15 Pareth-3, 2-
Methylresorcinol, N,N-Bis (2-Hydroxyethyl)-P-Phenylenediamine Sulfate, Tocopheryl Acetate,
Oleth-10, Panthenol, EDTA, M-Aminophenol, 1-Naphthol, P-Aminophenol

Natural Instincts Colorant: Shade M7
Water, Hexylene Glycol, Ethanolamine, Propylene Glycol, Soytrimonium Chloride, Trisodium
Ethylenediamine Disuccinate, Ethoxydiglycol, Oleth-5, C11-15 Pareth-9, Simmondsia Chinensis
(JOJOBA) Seed Extract, Panax Ginseng Root Extract, Aloe Barbadensis Flower Extract,
Anthemis Nobilis Flower Extract, Hydrolyzed Wheat Protein, Hydrolyzed Silk, Fragrance,
Polysorbate 20, P-Phenylenediamine, Oleth-2, Dilinoleic Acid, Cocamidopropyl Betaine, Oleic
Acid, Resorcinol, Erythorbic Acid, Sodium Sulfite, Oleamide MIPA, C12-15 Pareth-3, 2-
Methylresorcinol, Tocopheryl Acetate, Oleth-10, Panthenol, EDTA, M-Aminophenol, 1-
Naphthol, P-Aminophenol
Natural Instincts Colorant: Shade M9
Water, Hexylene Glycol, Ethanolamine, Propylene Glycol, Soytrimonium Chloride, Trisodium
Ethylenediamine Disuccinate, Ethoxydiglycol, Oleth-5, C11-15 Pareth-9, Simmondsia Chinensis
(JOJOBA) Seed Extract, Panax Ginseng Root Extract, Aloe Barbadensis Flower Extract,
Anthemis Nobilis Flower Extract, Hydrolyzed Wheat Protein, Hydrolyzed Silk, Fragrance,
Polysorbate 20, P-Phenylenediamine, Oleth-2, Dilinoleic Acid, Cocamidopropyl Betaine, Oleic
Acid, Resorcinol, Erythorbic Acid, Sodium Sulfite, Oleamide MIPA, C12-15 Pareth-3, 2-
Methylresorcinol, N,N-Bis (2-Hydroxyethyl)-P-Phenylenediamine Sulfate, Tocopheryl Acetate,
Oleth-10, Panthenol, EDTA, M-Aminophenol, 1-Naphthol, P-Aminophenol
Natural Instincts Colorant: Shade M11
Water, Hexylene Glycol, Ethanolamine, Propylene Glycol, Soytrimonium Chloride, Trisodium
Ethylenediamine Disuccinate, Ethoxydiglycol, Oleth-5, C11-15 Pareth-9, P-Phenylenediamine,
Simmondsia Chinensis (JOJOBA) Seed Extract, Panax Ginseng Root Extract, Aloe Barbadensis
Flower Extract, Anthemis Nobilis Flower Extract, Hydrolyzed Wheat Protein, Hydrolyzed Silk,
Fragrance, Polysorbate 20, Oleth-2, Dilinoleic Acid, Cocamidopropyl Betaine, Oleic Acid,
Resorcinol, Erythorbic Acid, Sodium Sulfite, Oleamide MIPA, C12-15 Pareth-3, 2-
Methylresorcinol, N,N-Bis (2-Hydroxyethyl)-P-Phenylenediamine Sulfate, Tocopheryl Acetate,
Oleth-10, Panthenol, EDTA, M-Aminophenol, 1-Naphthol, P-Aminophenol
Natural Instincts Colorant: Shade M13
Water, Hexylene Glycol, Ethanolamine, Propylene Glycol, Soytrimonium Chloride, Trisodium
Ethylenediamine Disuccinate, Ethoxydiglycol, P-Phenylenediamine, Oleth-5, C11-15 Pareth-9,
Simmondsia Chinensis (JOJOBA) Seed Extract, Panax Ginseng Root Extract, Aloe Barbadensis
Flower Extract, Anthemis Nobilis Flower Extract, Hydrolyzed Wheat Protein, Hydrolyzed Silk,
Fragrance, Polysorbate 20, Oleth-2, Dilinoleic Acid, Cocamidopropyl Betaine, Oleic Acid,
Resorcinol, Erythorbic Acid, Sodium Sulfite, Oleamide MIPA, C12-15 Pareth-3, 2-
Methylresorcinol, N,N-Bis (2-Hydroxyethyl)-P-Phenylenediamine Sulfate, Tocopheryl Acetate,
Oleth-10, Panthenol, EDTA, M-Aminophenol, 1-Naphthol
Natural Instincts Colorant: Shade M15
Water, Hexylene Glycol, Propylene Glycol, Ethanolamine, P-Phenylenediamine, N,N-Bis (2-
Hydroxyethyl)-P-Phenylenediamine Sulfate, Soytrimonium Chloride, Trisodium
Ethylenediamine Disuccinate, Ethoxydiglycol, Oleth-5, C11-15 Pareth-9, Resorcinol, Oleth-2,
Simmondsia Chinensis (Jojoba) Seed Extract, Panax Ginseng Root Extract, Aloe Barbadensis
Flower Extract, Anthemis Nobilis Flower Extract, Hydrolyzed Wheat Protein, Hydrolyzed Silk,
Fragrance, Polysorbate 20, Dilinoleic Acid, Cocamidopropyl Betaine, Oleic Acid, Erythorbic
Acid, Sodium Sulfite, Oleamide MIPA, C12-15 Pareth-3, Tocopheryl Acetate, Oleth-10,
Panthenol, EDTA, M-Aminophenol, 1-Naphthol

Natural Instincts Colorant: Shade M17
Water, Hexylene Glycol, Propylene Glycol, Ethanolamine, P-Phenylenediamine, N,N-Bis (2-
Hydroxyethyl)-P-Phenylenediamine Sulfate, Soytrimonium Chloride, Trisodium
Ethylenediamine Disuccinate, Ethoxydiglycol, Oleth-5, C11-15 Pareth-9, Resorcinol, Oleth-2,
Simmondsia Chinensis (JOJOBA) Seed Extract, Panax Ginseng Root Extract, Aloe Barbadensis
Flower Extract, Anthemis Nobilis Flower Extract, Hydrolyzed Wheat Protein, Hydrolyzed Silk,
Fragrance, Polysorbate 20, Dilinoleic Acid, Cocamidopropyl Betaine, Oleic Acid, Erythorbic
Acid, Sodium Sulfite, Oleamide MIPA, C12-15 Pareth-3, Tocopheryl Acetate, Oleth-10,
Panthenol, EDTA, M-Aminophenol, 1-Naphthol

Natural Instincts Colorant: Shade M19
Water, Hexylene Glycol, Propylene Glycol, Ethanolamine, P-Phenylenediamine, N,N-Bis (2-
Hydroxyethyl)-P-Phenylenediamine Sulfate, Soytrimonium Chloride, Trisodium
Ethylenediamine Disuccinate, Ethoxydiglycol, Oleth-5, C11-15 Pareth-9, Resorcinol,
Simmondsia Chinensis (JOJOBA) Seed Extract, Panax Ginseng Root Extract, Aloe Barbadensis
Flower Extract, Anthemis Nobilis Flower Extract, Hydrolyzed Wheat Protein, Hydrolyzed Silk,
Fragrance, Polysorbate 20, Oleth-2, Dilinoleic Acid, Cocamidopropyl Betaine, Oleic Acid,
Erythorbic Acid, Sodium Sulfite, Oleamide MIPA, C12-15 Pareth-3, Tocopheryl Acetate, Oleth-
10, Panthenol, EDTA, M-Aminophenol, 1-Naphthol
Natural Instincts Developing Lotion
Water, Hydrogen Peroxide, Acrylates Copolymer, Steareth-21, Oleth-2, Oleth-5, PEG-50
Hydrogenated Palmamide, Acrylates/Steareth-20 Methacrylate Copolymer, Oleyl Alcohol,
Etidronic Acid, Disodium EDTA, Simethicone

Natural Instincts Color Conditioning Treatment
Water, Amodimethicone, Stearyl Alcohol, Cetyl Alcohol, Stearamidopropyl Dimethylamine,
Glutamic Acid, Fragrance, Benzyl Alcohol, Panthenyl Ethyl Ether, EDTA, Panthenol,
Trimethylsiloxysilicate, Carthamus Tinctorius (Safflower) Seed Oil, Cocos Nucifera (Coconut)
Oil, Hydrolyzed Sweet Almond Protein, Methylchloroisothiazolinone, Methylisothiazolinone,
Aloe Barbadensis Leaf
Hazardous Ingredients contained in the Developing Lotion, as defined by OSHA, 29 CFR
1910.1200 and/or WHMIS under the HPA:

SECTION 4 - FIRST AID MEASURES
Eye:
Following accidental eye exposure, thorough rinsing of the affected area for 15-20 minutes with
clean, cold water is recommended. If discomfort or irritation persists, contact a physician. If
the eyes or face becomes swollen during or following use, consult a physician or emergency
room immediately.
Skin Problem:
Thoroughly rinse with water. Discontinue use of product. If discomfort persists and/or the skin
reaction worsens, contact a physician immediately. In cases where discomfort persists and/or
medical attention is sought, do not use hair color products again until the specific nature of the
skin reaction and the causative agent has been identified by a dermatologist, and appropriate
medical advice provided.
Inhalation:
If respiratory irritation occurs, remove individual to fresh air.
Ingestion:
Accidental ingestion of product may necessitate medical attention. In case of accidental
ingestion dilute with fluids (water or milk) and treat symptomatically. Do not induce vomiting.
Note: After first aid treatment, the caller should be advised that 1) a hospital emergency room or
family physician should be consulted if anything unusual occurs or appears necessary in the
judgment of the caller, and 2) that the subsequent management of the accident should be dictated
by any persistent symptoms and under the direction of the physician.

SECTION 5 - FIRE FIGHTING MEASURES
Flash Point & Method: Not applicable.
Extinguishing Media: Use chemical foam, dry chemical, carbon dioxide or water.
Explosion Hazard: No applicable information has been found. Material will not burn.
Fire Fighting Instructions: Contact emergency personnel. Use self-contained breathing
apparatus and full protective gear, if large quantities of product are involved. Hazardous decomposition products may be released. Thermal degradation may produce oxides of carbon and/or nitrogen; hydrocarbons and/or derivatives. Thermal degradation may also produce oxides of silicone. Decomposition of hydrogen peroxide will release oxygen which will increase the explosive limit range and burning rate of flammable materials. SECTION 6 - ACCIDENTAL RELEASE MEASURES
Procedures for Spill/Leak Clean-up:
For Household Settings:
Absorb spills with inert material. Dilute with water. Absorb liquid
and scrub the area with detergent.

For Non-Household Settings:
Avoid exposure to, or contamination with, liquid organic
materials or damp organic materials (e.g., wet paper towels, wood, clothing, etc.). If
contaminated, spontaneous combustion may occur. Use safety glasses or safety goggles if splash
hazards exist; use gloves and other protective clothing (apron, boots, etc) to prevent skin contact.


SECTION 7 - HANDLING AND STORAGE
Precautions for Safe Handling:

For Household Settings:
Avoid contact with eyes, skin and clothing.

For Non-Household Settings:
Avoid contamination with combustible organic matter (e.g., oil, sawdust, damp paper towels,
etc.), metal, powder or reducing agents. Contamination may cause decomposition, leading to
fire. Decomposition of oxidizing material releases oxygen which may intensify existing fires.
Conditions for Safe Storage:
For Household Settings:
Keep in cool place. Avoid contamination. Keep closed when not in use. Store in the original
tightly capped containers away from sunlight, heat, sparks and flame. Do not store any tint,
lightener lotion or bleach powder after it has been mixed with developer; the container may
rupture. Never return unused material to original container. Empty containers should be rinsed
with water before discarding. Keep out of reach of children. Decomposition of hydrogen
peroxide may occur with increase in pressure and possible container rupture.

For Non-Household Settings:

Store in a well ventilate, cool area. Avoid contamination. Store in the original tightly capped
containers away from sunlight, heat, sparks and flame. Decomposition of hydrogen peroxide
may occur with increase in pressure and possible container rupture.

Other Recommendations:
None.


SECTION 8 – EXPOSURE CONTROLS, PERSONAL PROTECTION
For Household Settings:
This is a personal care or cosmetic product that is safe for consumers and other users under
normal and reasonably foreseen use.
For Non-Household Settings:
Use safety glasses or safety goggles if splash hazards exist; use gloves and other protective
clothing (apron, boots, etc) to prevent skin contact. Always follow good hygienic work
practices. Avoid prolonged contact with skin and clothing.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Color, Odor and Appearance:
Melting Point:
Colorant: Yellow to dark amber, may also
Colorant: Not Applicable.
appear orange to reddish, clear to slightly Developing Lotion: Not Applicable.
Color Conditioning Treatment: Not
Developing Lotion: creamy white liquid
with characteristic odor
Color Conditioning Treatment:
Light
creamy white, creamy, moundy, with
characteristic odor.
Physical State:
Boiling Point:
Colorant: Viscous liquid.
Colorant: >212°F (100°C).
Developing Lotion: Viscous liquid
Developing Lotion: >212°F (100°C).
Color Conditioning Treatment: Viscous
Color Conditioning Treatment: >212°F
Solubility in Water:
Colorant: 9.0-11.0
Colorant: Slightly insoluble.
Developing Lotion: 2.4-3.5
Developer: Slightly insoluble
Color Conditioning Treatment: 4.8 -5.8
Color Conditioning Treatment: Slightly
insoluble.
Flashpoint:
% VOC:
Colorant: Not Applicable.
Developing Lotion: Not Applicable.
Color Conditioning Treatment: Not
Vapor Density:
Specific Gravity:
Colorant: Not Applicable.
Colorant: 1.00-1.02
Developing Lotion: Not Applicable.
Developing Lotion: > 0.98
Color Conditioning Treatment: Not
Color Conditioning Treatment: > 0.95
SECTION 10 - STABILITY AND REACTIVITY
Conditions to Avoid: Store away from flammable liquids, flammable solids, aerosols and
other incompatible materials. Avoid contamination. Do not store any tint, lightener lotion or bleach powder after it has been mixed with developer; the container may rupture. Never return unused material to original container. Avoid extreme heat and ignition sources.
Other Recommendations: None.

SECTION 11 - TOXICOLOGICAL INFORMATION
This is a personal care or cosmetic product that is safe for consumers and other users under
intended and reasonably foreseeable use. Additional information on toxicological endpoints is
available from the supplier upon request.
This product contains ingredients which may cause skin irritation on certain individuals and a
preliminary test according to accompanying directions should first be made. This product must
not be used for dyeing the eyelashes or eyebrows; to do so may cause blindness.

Chronic Effects:
Finished product is not expected to have chronic health effects.
Target Organs: No adverse health effects on target organs expected for finished product.
Carcinogenicity: Finished product is not expected to be carcinogenic.
NTP: No IARC: No OSHA: No
SECTION 12 - ECOLOGICAL INFORMATION
The product ingredients are expected to be safe for the environment at concentrations predicted under normal use and accidental spill scenarios. Packaging components are compatible with the conventional solid waste management practices. Additional information is available from the supplier on request. SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal should be in accordance with Federal, State/Provincial and Local regulations.
For Household Settings:
The following instructions are for consumer usage only. Do not discharge product into natural
waters without pre-treatment or adequate dilution.
For Non-Household Settings:
Products covered by this MSDS, in their original form, when disposed as waste, are considered
non hazardous waste according to Federal RCRA regulations (40 CFR 261). Disposal should be
in accordance with local, state and federal regulations.
California Waste Code: 331
SECTION 14 - TRANSPORT INFORMATION
Finished packaged product transported by ground (DOT): Non hazardous Finished packaged product transported by vessel (IMDG): Non hazardous Finished packaged product transported by air (IATA): Non hazardous SECTION 15 - ADDITIONAL REGULATORY INFORMATION
EU DPD (Dangerous Products Directive) Classification (DPD 88/379/EEC).
Regulated as a Cosmetic and/or Drug under FDA (US), HPB (Canada), Cosmetic Directive
(EU), MHW (Japan) and MOH (China).
While the finished product(s) is not considered hazardous as defined in 29 CFR 1910.1200 (d),
this MSDS contains valuable information critical to the safe handling and proper use of the
product.
US Federal
The product described in this Material Safety Data Sheet is regulated under the Federal Food,
Drug, and Cosmetics Act and is safe to use as per directions on container, box or accompanying
literature (where applicable).
CERCLA reportable quantity (RQ):
Colorant:

Ingredient CAS
(Ethoxydiglycol) P-Phenylenediamine 106-50-3
SARA 313/302/304/311/312 chemicals:
Colorant:

Ingredient
313 302 304 311 312

Canada

All ingredients are CEPA approved for import to Canada. This product has been classified in
accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and
this MSDS contains all information required by the CPR.
US States
CA Prop 65:
This product is not subject to warning labeling under California Proposition 65.

State Right-to-Know:
The following ingredients are present in the finished product and are listed on the following state
right-to-know lists:
Colorant:
Ingredient

Developing Lotion:

Ingredient

Color Conditioning Treatment:

Ingredient

Other
Perfumes contained within the products covered by this MSDS comply with appropriate IFRA
guidance.
SECTION 16 - OTHER INFORMATION
DISCLAIMER: This MSDS is intended to provide a brief summary of our knowledge and
guidance regarding the use of this material. The information contained here has been compiled
from sources considered by Procter & Gamble to be dependable and is accurate to the best of the
Company’s knowledge. It is not meant to be an all-inclusive document on worldwide hazard
communication regulations.
This information is offered in good faith. Each user of this material needs to evaluate the
conditions of use and design the appropriate protective mechanisms to prevent employee
exposures, property damage or release to the environment. Procter & Gamble assumed no
responsibility for injury to the recipient or third persons, or for any damage to any property
resulting from misuse of the product.


Source: http://www.grupovita.es/content/pdf/01_about_pg/msds/beauty_care/Hair_Color/Natural_Instincts_For_Men_(08-07).pdf

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