Chemwatch australian msds 4795-85

ICCONS M50E,MC50 STYRENE FREE POLYESTER ADHESIVE INJECTION
Chemwatch Independent Material Safety Data Sheet
Issue Date: 21-Mar-2013
CHEMWATCH 4795-85
Version No:5.1.1.1
CD 2013/1 Page 1 of 14
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
ICCONS M50E,MC50 STYRENE FREE POLYESTER ADHESIVE INJECTION
SYNONYMS
"Iccons M50E, MC50 Styrene Free Polyester Adhesive Injection"
PRODUCT USE
A chemical anchoring application.
SUPPLIER
Company: Iccons Pty Ltd
Address:
12 Produce Drive
Dandenong South
VIC, 3175
Australia
Telephone: +61 3 9706 4344
Emergency Tel: 1800 039 008 (24hrs)
Emergency Tel: +61 3 9573 112
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to NOHSC Criteria, and ADG Code.
RISK
Risk Codes
• Harmful to aquatic organisms, may cause long- term adverseeffects in the aquatic environment.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
Section 4 - FIRST AID MEASURES
SWALLOWED
• If swallowed do NOT induce vomiting.
• If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to
maintain open airway and prevent aspiration.
• Observe the patient carefully.
• Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming
unconscious.
continued.
ICCONS M50E,MC50 STYRENE FREE POLYESTER ADHESIVE INJECTION
Chemwatch Independent Material Safety Data Sheet
Issue Date: 21-Mar-2013
CHEMWATCH 4795-85
Version No:5.1.1.1
CD 2013/1 Page 2 of 14
Section 4 - FIRST AID MEASURES
• Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
• Seek medical advice.
EYE
■ If this product comes in contact with the eyes:
• Wash out immediately with fresh running water.
• Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by
occasionally lifting the upper and lower lids.
• Seek medical attention without delay; if pain persists or recurs seek medical attention.
• Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
SKIN
■ If skin contact occurs:
• Immediately remove all contaminated clothing, including footwear.
• Flush skin and hair with running water (and soap if available).
• Seek medical attention in event of irritation.
INHALED
• If fumes or combustion products are inhaled remove from contaminated area.
• Lay patient down. Keep warm and rested.
• Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to
initiating first aid procedures.
• Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask
device, or pocket mask as trained. Perform CPR if necessary.
• Transport to hospital, or doctor.
NOTES TO PHYSICIAN
■ For acute or short term repeated exposures to styrene:
INHALATION:
•
Severe exposures should have cardiac monitoring to detect arrhythmia.
• Catecholamines, especially epinephrine (adrenaline) should be used cautiously (if at all).
• Aminophylline and inhaled beta-two selective bronchodilators (e.g. salbutamol) are the drugs of choice for Ipecac syrup should be given for ingestions exceeding 3ml (styrene)/kg.
• For patients at risk of aspiration because of obtundation, intubation should precede lavage.
• Pneumonitis is a significant risk. Watch the patient closely in an upright (alert patient) or left lateral head-down position (obtunded patient) to reduce aspiration potential. [Ellenhorn and Barceloux: MedicalToxicology] BIOLOGICAL EXPOSURE INDEX - BEIThese represent the determinants observed in specimens collected from a healthy worker who has been exposed at the Exposure Standard (ES or TLV):Determinant NS: Non-specific determinant; also seen after exposure to other materials.
SQ: Semi-quantitative determinant - Interpretation may be ambiguous; should be used as a screening test or B: Background levels occur in specimens collected from subjects NOT exposed.
continued.
ICCONS M50E,MC50 STYRENE FREE POLYESTER ADHESIVE INJECTION
Chemwatch Independent Material Safety Data Sheet
Issue Date: 21-Mar-2013
CHEMWATCH 4795-85
Version No:5.1.1.1
CD 2013/1 Page 3 of 14
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
• Foam.
• Dry chemical powder.
• BCF (where regulations permit).
• Carbon dioxide.
• Water spray or fog - Large fires only.
FIRE FIGHTING
• Alert Fire Brigade and tell them location and nature of hazard.
• Wear breathing apparatus plus protective gloves.
• Prevent, by any means available, spillage from entering drains or water courses.
• Use water delivered as a fine spray to control fire and cool adjacent area.
• DO NOT approach containers suspected to be hot.
• Cool fire exposed containers with water spray from a protected location.
• If safe to do so, remove containers from path of fire.
• Equipment should be thoroughly decontaminated after use.
FIRE/EXPLOSION HAZARD
• Combustible.
• Slight fire hazard when exposed to heat or flame.
• Heating may cause expansion or decomposition leading to violent rupture of containers.
• On combustion, may emit toxic fumes of carbon monoxide (CO).
• May emit acrid smoke.
• Mists containing combustible materials may be explosive.
Combustion products include: carbon monoxide (CO), carbon dioxide (CO2), other pyrolysis products typical of
burning organic material.
May emit poisonous fumes.
May emit corrosive fumes.
FIRE INCOMPATIBILITY
• Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine
HAZCHEM
None
Section 6 - ACCIDENTAL RELEASE MEASURES
MINOR SPILLS
• Clean up all spills immediately.
• Avoid contact with skin and eyes.
• Wear impervious gloves and safety goggles.
• Trowel up/scrape up.
• Place spilled material in clean, dry, sealed container.
• Flush spill area with water.
MAJOR SPILLS
• Clear area of personnel and move upwind.
• Alert Fire Brigade and tell them location and nature of hazard.
• Wear breathing apparatus plus protective gloves.
• Prevent, by any means available, spillage from entering drains or water course.
• Stop leak if safe to do so.
• Contain spill with sand, earth or vermiculite.
• Collect recoverable product into labelled containers for recycling.
continued.
ICCONS M50E,MC50 STYRENE FREE POLYESTER ADHESIVE INJECTION
Chemwatch Independent Material Safety Data Sheet
Issue Date: 21-Mar-2013
CHEMWATCH 4795-85
Version No:5.1.1.1
CD 2013/1 Page 4 of 14
Section 6 - ACCIDENTAL RELEASE MEASURES
• Neutralise/decontaminate residue (see Section 13 for specific agent).
• Collect solid residues and seal in labelled drums for disposal.
• Wash area and prevent runoff into drains.
• After clean up operations, decontaminate and launder all protective clothing and equipment before storing • If contamination of drains or waterways occurs, advise emergency services.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
• Limit all unnecessary personal contact.
• Wear protective clothing when risk of exposure occurs.
• Use in a well-ventilated area.
• Avoid contact with incompatible materials.
• When handling, DO NOT eat, drink or smoke.
• Keep containers securely sealed when not in use.
• Avoid physical damage to containers.
• Always wash hands with soap and water after handling.
• Work clothes should be laundered separately.
• Use good occupational work practice.
• Observe manufacturer's storage and handling recommendations contained within this MSDS.
• Atmosphere should be regularly checked against established exposure standards to ensure safe working
conditions are maintained.
SUITABLE CONTAINER
• Metal can or drum
• Packaging as recommended by manufacturer.
• Check all containers are clearly labelled and free from leaks.
STORAGE INCOMPATIBILITY
■ Vinyl toluene (syn: methylstyrene)
• polymerises explosively unless inhibited with, typically, 10-50 ppm tert-butylcatechol
• reacts violently with strong oxidisers, strong acids, peroxides
• is incompatible with aluminium chloride, ammonia, aliphatic amines, alkanolamides, caustics, metal salts
• uninhibited monomer may block vents and confined spaces by forming a solid polymeric material.
• Avoid reaction with oxidising agents.
STORAGE REQUIREMENTS
• Store in original containers.
• Keep containers securely sealed.
• No smoking, naked lights or ignition sources.
• Store in a cool, dry, well-ventilated area.
• Store away from incompatible materials and foodstuff containers.
• Protect containers against physical damage and check regularly for leaks.
• Observe manufacturer's storage and handling recommendations contained within this MSDS.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
continued.
ICCONS M50E,MC50 STYRENE FREE POLYESTER ADHESIVE INJECTION
Chemwatch Independent Material Safety Data Sheet
Issue Date: 21-Mar-2013
CHEMWATCH 4795-85
Version No:5.1.1.1
CD 2013/1 Page 5 of 14
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Styrene Free PolyesterAdhesive Injection(Vinyl toluene) Styrene Free PolyesterAdhesive Injection(Benzoyl peroxide) The following materials had no OELs on our records• 2- ethylhexylbenzoate: EMERGENCY EXPOSURE LIMITS
Material
Revised IDLH Value (mg/m3)
Revised IDLH Value (ppm)
MATERIAL DATA
ICCONS M50E,MC50 STYRENE FREE POLYESTER ADHESIVE INJECTION:
■ None assigned. Refer to individual constituents.
■ as vinyl toluene (syn: methylstyrene)IDLH Level: 5000 ppmThe toxicological properties of vinyltoluene are similar to those of styrene and the TLV- TWA and STEL are analogous. The limits are thought to be protective against mucous membrane and ocular irritation and shouldreduce the complaints of objectionable odour. Given that axonal degeneration found in rats inhalingvinyltoluene is more significant than in rats inhaling comparable concentrations of styrene, and thatneurological changes are more prominent, the limits are the subject of review.
Human subjects show ocular and upper respiratory tract irritation at 400 ppm, complain of a strong objectionable odour at 300 ppm and a strong but tolerable odour at 200 ppm. At 50 ppm, the odour isdetectable and may become disagreeable, but does not produce irritation of the mucous membranes.
For p-tert-butylcatechol:CEL TWA: 5 mg/m3 (CEL = Chemwatch Exposure Limit)4-tert-Butylcatechol is severely irritating, can cause allergic dermatitis and can depigment skin. The American Industrial Hygiene Association has recommended a Workplace Exposure Level (WEEL) for an 8-hr timeweighted average (TWA) of 5 mg/m3 to protect against acute irritant effects. Oral effects are only slight andgenerally reversible.
Exposed individuals are reasonably expected to be warned, by smell, that the Exposure Standard is being Odour Safety Factor (OSF) is determined to fall into either Class A or B.
The Odour Safety Factor (OSF) is defined as:OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppmClassification into classes follows: Over 90% of exposed individualsare aware by smell that theExposure Standard (TLV- TWA forexample) is being reached, evenwhen distracted by workingactivities As " A" for 50- 90% of personsbeing distracted continued.
ICCONS M50E,MC50 STYRENE FREE POLYESTER ADHESIVE INJECTION
Chemwatch Independent Material Safety Data Sheet
Issue Date: 21-Mar-2013
CHEMWATCH 4795-85
Version No:5.1.1.1
CD 2013/1 Page 6 of 14
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
As " A" for less than 50% ofpersons being distracted 10- 50% of persons aware ofbeing tested perceive by smellthat the Exposure Standard isbeing reached As " D" for less than 10% ofpersons aware of being tested ■ No exposure limits set by NOHSC or ACGIH.
■ For benzoyl peroxide:The recommendation for the TLV-TWA is based on the absence of subjective symptoms of irritation of the nose and throat in humans exposed to 5.25 mg/m3. Whether this is sufficiently low to prevent cumulativeeffects in man is not known.
PERSONAL PROTECTION
EYE
• Safety glasses with side shields.
• Chemical goggles.
• Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A
written policy document, describing the wearing of lens or restrictions on use, should be created for eachworkplace or task. This should include a review of lens absorption and adsorption for the class ofchemicals in use and an account of injury experience. Medical and first-aid personnel should be trained intheir removal and suitable equipment should be readily available. In the event of chemical exposure, begineye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at thefirst signs of eye redness or irritation - lens should be removed in a clean environment only after workershave washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or nationalequivalent].
HANDS/FEET
• Wear chemical protective gloves, e.g. PVC.
• Wear safety footwear or safety gumboots, e.g. Rubber.
NOTE:
• The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing
gloves and other protective equipment, to avoid all possible skin contact.
• Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.
OTHER
• Overalls.
• P.V.C. apron.
• Barrier cream.
• Skin cleansing cream.
• Eye wash unit.
RESPIRATOR
•Type A-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national
equivalent)
■ Cartridge respirators should never be used for emergency ingress or in areas of unknown vapour
concentrations or oxygen content. The wearer must be warned to leave the contaminated area immediately on
detecting any odours through the respirator. The odour may indicate that the mask is not functioning properly,
that the vapour concentration is too high, or that the mask is not properly fitted. Because of these
limitations, only restricted use of cartridge respirators is considered appropriate.
continued.
ICCONS M50E,MC50 STYRENE FREE POLYESTER ADHESIVE INJECTION
Chemwatch Independent Material Safety Data Sheet
Issue Date: 21-Mar-2013
CHEMWATCH 4795-85
Version No:5.1.1.1
CD 2013/1 Page 7 of 14
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
The local concentration of material, quantity and conditions of use determine the type of personal protectiveequipment required. For further information consult site specific CHEMWATCH data (if available), or yourOccupational Health and Safety Advisor.
ENGINEERING CONTROLS
■ Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-
designed engineering controls can be highly effective in protecting workers and will typically be independent
of worker interactions to provide this high level of protection.
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.
Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker
and ventilation that strategically "adds" and "removes" air in the work environment. Ventilation can remove
or dilute an air contaminant if designed properly. The design of a ventilation system must match the
particular process and chemical or contaminant in use.
Employers may need to use multiple types of controls to prevent employee overexposure.
Local exhaust ventilation usually required. If risk of overexposure exists, wear approved respirator. Correctfit is essential to obtain adequate protection. Supplied-air type respirator may be required in specialcircumstances. Correct fit is essential to ensure adequate protection.
An approved self contained breathing apparatus (SCBA) may be required in some situations.
Provide adequate ventilation in warehouse or closed storage area.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Coloured paste with a sweet odour; does not mix with water.
PHYSICAL PROPERTIES
Section 10 - STABILITY AND REACTIVITY
CONDITIONS CONTRIBUTING TO INSTABILITY
• Presence of incompatible materials.
• Product is considered stable.
• Hazardous polymerisation will not occur.
For incompatible materials - refer to Section 7 - Handling and Storage.
continued.
ICCONS M50E,MC50 STYRENE FREE POLYESTER ADHESIVE INJECTION
Chemwatch Independent Material Safety Data Sheet
Issue Date: 21-Mar-2013
CHEMWATCH 4795-85
Version No:5.1.1.1
CD 2013/1 Page 8 of 14
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
■ The material has NOT been classified by EC Directives or other classification systems as "harmful by
ingestion". This is because of the lack of corroborating animal or human evidence. The material may still be
damaging to the health of the individual, following ingestion, especially where pre-existing organ (eg. liver,
kidney) damage is evident. Present definitions of harmful or toxic substances are generally based on doses
producing mortality rather than those producing morbidity (disease, ill-health). Gastrointestinal tract
discomfort may produce nausea and vomiting. In an occupational setting however, ingestion of insignificant
quantities is not thought to be cause for concern.
EYE
■ Although the material is not thought to be an irritant (as classified by EC Directives), direct contact
with the eye may produce transient discomfort characterised by tearing or conjunctival redness (as with
windburn).
SKIN
■ The material is not thought to produce adverse health effects or skin irritation following contact (as
classified by EC Directives using animal models). Nevertheless, good hygiene practice requires that exposure
be kept to a minimum and that suitable gloves be used in an occupational setting.
Open cuts, abraded or irritated skin should not be exposed to this material.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury
with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage
is suitably protected.
INHALED
■ The material is not thought to produce respiratory irritation (as classified by EC Directives using animal
models). Nevertheless inhalation of the material, especially for prolonged periods, may produce respiratory
discomfort and occasionally, distress.
Inhalation of vapours or aerosols (mists, fumes), generated by the material during the course of normal
handling, may be damaging to the health of the individual.
Central nervous system (CNS) depression is seen at styrene exposures exceeding 50 ppm, whilst headache,
fatigue, nausea and dizziness are seen consistently at exposures of 100 ppm. Evidence exists that at 100 ppm,
5-10% reductions in sensory nerve conductions occur, and after exposure to 50 ppm, there is slowing of
reaction times. Exposure at 370 ppm produces unpleasant subjective symptoms and signs of neurological
impairment. High vapour concentrations may have a toxic and anaesthetic effect, which may lead to
unconsciousness or death. Exposure at 0.1% can lead rapidly to unconsciousness whilst exposure to 1% can
cause death in less than one hour. Simple reaction times were increased and co-ordination decreased amongst
volunteers inhaling 350 ppm (via mouth tube) for 30 minutes. Controlled inhalation studies with 300 ppm (via
mouth tube) for one hour found reduced eye tracking abilities but no changes in balance or co-ordination.
CHRONIC HEALTH EFFECTS
■ Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-
term occupational exposure.
There is limited evidence that, skin contact with this product is more likely to cause a sensitisation
reaction in some persons compared to the general population.
Based on experience with animal studies, there is a possibility that exposure to the material may result in
toxic effects to the development of the foetus, at levels which do not cause significant toxic effects to the
mother.
Exposure to styrene may aggravate central nervous system disorders, chronic respiratory disease, skin disease,
kidney disease and liver disease. Exposure to styrene at work causes effects on the nervous system. It causes
a reversible loss in the ability to tell apart colours, and effects on hearing have been reported. Animal
testing has revealed toxicity to the lung and nose. It is unclear whether styrene can cause miscarriage.
Styrene can cause chromosomal damage, but there is little evidence that it causes congenital deformities in
continued.
ICCONS M50E,MC50 STYRENE FREE POLYESTER ADHESIVE INJECTION
Chemwatch Independent Material Safety Data Sheet
Issue Date: 21-Mar-2013
CHEMWATCH 4795-85
Version No:5.1.1.1
CD 2013/1 Page 9 of 14
Section 11 - TOXICOLOGICAL INFORMATION
TOXICITY AND IRRITATION
■ unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
DIBENZOYL PEROXIDE:METHYLSTYRENE, MIXED ISOMERS:■ The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated orprolonged exposure to irritants may produce conjunctivitis.
2-ETHYLHEXYLBENZOATE:METHYLSTYRENE, MIXED ISOMERS:■ No significant acute toxicological data identified in literature search.
ICCONS M50E,MC50 STYRENE FREE POLYESTER ADHESIVE INJECTION:Not available.
Oral (mouse) LD50:3160 mg/kgInhalation (mouse) LC50:3020 mg/m³/4hInhalation (Human) TCLo:400 ppm/4h■ The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skinredness, swelling, the production of vesicles, scaling and thickening of the skin.
Olfaction and eye effects recorded Subcutaneous (Rat) LD:40 mg/kg (@ 50%)Intraperitoneal (Mouse) LD50:440 mg/kgIntravenous (Rabbit) LD:16 mg/kg■ Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke'soedema. The pathogenesis of contact eczema involves a cell-mediated (T lymphocytes) immune reaction of thedelayed type. Other allergic skin reactions, e.g. contact urticaria, involve antibody-mediated immunereactions. The significance of the contact allergen is not simply determined by its sensitisation potential:the distribution of the substance and the opportunities for contact with it are equally important. A weaklysensitising substance which is widely distributed can be a more important allergen than one with strongersensitising potential with which few individuals come into contact. From a clinical point of view, substancesare noteworthy if they produce an allergic test reaction in more than 1% of the persons tested.
The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skinredness, swelling, the production of vesicles, scaling and thickening of the skin.
Benzoyl peroxide may cause double vision, breathing problems, excess saliva and tear formation, redness ofthe skin and changes in motor activity. It did not produce blood or biochemical adverse effects, genemutation or evidence of cancer. Repeated oral administration may result in decreased weights of testes andthe newborn.
The substance is classified by IARC as Group 3:NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
continued.
ICCONS M50E,MC50 STYRENE FREE POLYESTER ADHESIVE INJECTION
Chemwatch Independent Material Safety Data Sheet
Issue Date: 21-Mar-2013
CHEMWATCH 4795-85
Version No:5.1.1.1
CD 2013/1 Page 10 of 14
Section 11 - TOXICOLOGICAL INFORMATION
CARCINOGEN
methylstyrene,
SKIN
methylstyrene, mixed
GESAMP/EHS Composite List - GESAMP Hazard Section 12 - ECOLOGICAL INFORMATION
2-ETHYLHEXYLBENZOATE:DIBENZOYL PEROXIDE:METHYLSTYRENE, MIXED ISOMERS:■ DO NOT discharge into sewer or waterways.
2-ETHYLHEXYLBENZOATE:METHYLSTYRENE, MIXED ISOMERS:■ Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean highwater mark. Do not contaminate water when cleaning equipment or disposing of equipment wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste sites.
METHYLSTYRENE, MIXED ISOMERS:Marine Pollutant ■ Toxic to aquatic organisms.
May cause long-term adverse effects in the aquatic environment.
For styrene:Transport: Styrene is expected to volatilise from surface waters, and is also removed from waters byadsorption onto soils and sediments. Under certain conditions, styrene may leach through soil (particularlysandy soils) and enter ground water.
Transformation/Persistence: Air - In the atmosphere, styrene reacts with both hydroxyl radicals and ozonewith estimated half-lives of 3.5 and 9 hours, respectively. The chemical is also degraded in the presence ofNOX and natural sunlight. Styrene contributes to the formation of photochemical smog. Smog chamberexperiments with simulated sunlight and auto exhaust as a source of styrene, showed a 55% disappearance ofstyrene in 2 hours. Soil - Biodegradation is the major route of removal of styrene from soils. Microbesisolated from landfill soil degraded 95% of the styrene present in 16 weeks. Water - Styrene rapidlyvolatilises from surface water with estimated half-lives from a river or pond of 0.6 days and 13 days,respectively. Microbial degradation of styrene in unadapted sewage sludge was 42% in 5 days while themicrobial degradation with adapted sewage sludge was 80% in 5 days.
Biota: Styrene is not likey to accumulate in biological organisms.
Ecotoxicity: Styrene is moderately toxic to aquatic organisms with toxicity values in the range of >1 mg/L to100 mg/L. Styrene is expected to have low toxicity towards terrestrial animals. Fish LC50 (96 h): Lepomismacrochirus (blue gill) 25 mg/l; Pimephales promelas (fathead minnow) 46.4 mg/l (soft water); Carassiusauratus (goldfish) 64.74 mg/l; Lebistes reticulatus (guppy) 74.83 mg/lDaphnia magna LC50 (48 h): 23 mg/l; (24h): 27 mg/l.
Substances containing unsaturated carbons are ubiquitous in indoor environments. They result from many continued.
ICCONS M50E,MC50 STYRENE FREE POLYESTER ADHESIVE INJECTION
Chemwatch Independent Material Safety Data Sheet
Issue Date: 21-Mar-2013
CHEMWATCH 4795-85
Version No:5.1.1.1
CD 2013/1 Page 11 of 14
Section 12 - ECOLOGICAL INFORMATION
sources (see below). Most are reactive with environmental ozone and many produce stable products which arethought to adversely affect human health.The potential for surfaces in an enclosed space to facilitatereactions should be considered.
decanal, 9- oxo- nonanoic acid,azelaic acid, nonanoic acid.
pinonic acid, formic acid,methacrolein, methyl vinylketone, SOAs including ultrafineparticles heptenal, 2- nonenal, 2-decenal, 1- pentene- 3- one,propionic acid, n- butyric acid benzaldehyde, 4- hydroxy- 4-methyl- 5- hexen- 1- al, 5-ethenyl- dihydro- 5- methyl-2(3H)- furanone, 4- AMC, SOAsincluding ultrafine particles Formaldehyde, methacrolein,methyl vinyl ketone paper, styrene polymersEnvironmental tobacco smoke Formaldehyde, benzaldehyde,hexanal, glyoxal, N-methylformamide,nicotinaldehyde, cotinine decanal, 9- oxo- nonanoic acid,azelaic acid, nonanoic acid acid and other oxo- acids;compounds with mixed functionalgroups (=O, - OH, and - COOH) continued.
ICCONS M50E,MC50 STYRENE FREE POLYESTER ADHESIVE INJECTION
Chemwatch Independent Material Safety Data Sheet
Issue Date: 21-Mar-2013
CHEMWATCH 4795-85
Version No:5.1.1.1
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Section 12 - ECOLOGICAL INFORMATION
methyl- 2(3H) furanone, SOAsincluding ultrafine particles Formaldehyde, 4- AMC,pinonaldehyde, acetone, pinicacid, pinonic acid, formic acid,benzaldehyde, SOAs includingultrafine particles Abbreviations: 4-AMC, 4-acetyl-1-methylcyclohexene; 6MHQ, 6-methyl-5-heptene-2-one, 4OPA, 4-oxopentanal, SOA, Secondary Organic AerosolsReference: Charles J Weschler; Environmental Helath Perspectives, Vol 114, October 2006.
■ Very toxic to aquatic organisms.
DIBENZOYL PEROXIDE:Half- life Soil - High (hours): Aqueous biodegradation - Aerobic - High (hours): Aqueous biodegradation - Aerobic - Low (hours): Aqueous biodegradation - Anaerobic - High (hours): Aqueous biodegradation - Anaerobic - Low (hours): Photolysis maximum light absorption - High (nano- m): Photolysis maximum light absorption - Low (nano- m): Photooxidation half- life air - High (hours): Photooxidation half- life air - Low (hours): ■ For benzoyl peroxide:Benzoyl peroxide has a melting point of 104 -106 °C, vapor pre ssure of 0.00929 Pa, solubility of 9.1 mg/L inwater at 25 C, and log Pow of 3.43 at 25 C.
Environmental Fate: For indirect photolysis in the atmosphere, the half-life is estimated to be 3 days. Thesubstance is readily biodegradable and hydrolyses rapidly in water. The main hydrolysis product of benzoylperoxide is benzoic acid. The estimated BCF of 92 suggests that the chemical has a low potential forbioaccumulation. Benzoyl peroxide is most likely to partition to water, where it will remain.
Ecotoxicity: Green algae (Selenastrum capricornutum) EbC50 (72 h): 0.07 mg/L (biomass) and 0.44 mg/L (growthrate).
Daphnia magna: EC50 (48 h): Fish LC50 (96 h): Oryzias latipes 0.24 mg/L.
Microorganism (activated sludge):EC50 (30 min): 35 mg/LThe toxicity observed is assumed to be due to benzoyl peroxide rather than benzoic acid, which shows muchlower toxicity to aquatic organisms. One can assume that effects occur before hydrolysis takes place.
Ecotoxicity
Ingredient
continued.
ICCONS M50E,MC50 STYRENE FREE POLYESTER ADHESIVE INJECTION
Chemwatch Independent Material Safety Data Sheet
Issue Date: 21-Mar-2013
CHEMWATCH 4795-85
Version No:5.1.1.1
CD 2013/1 Page 13 of 14
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
• Recycle wherever possible or consult manufacturer for recycling options.
• Consult State Land Waste Authority for disposal.
• Bury or incinerate residue at an approved site.
• Recycle containers if possible, or dispose of in an authorised landfill.
Section 14 - TRANSPORTATION INFORMATION
HAZCHEM:
None
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: ADG7, IATA, IMDG Section 15 - REGULATORY INFORMATION
REGULATIONS
Regulations for ingredients
methylstyrene, mixed isomers (CAS: 1321-45-5,25013-15-4) is found on the following regulatory
lists;
"Australia - Victoria Drugs, Poisons and Controlled Substances (Precursor Chemicals) Regs 2007 - Schedule 1 - Precursor Chemicals and Quantities","Australia
Dangerous Goods Code (ADG Code) - Goods Too Dangerous To Be Transported","Australia Exposure Standards","Australia Hazardous Substances","Australia Inventory
of Chemical Substances (AICS)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)","Australia Standard for
the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5","FisherTransport Information","GESAMP/EHS Composite List - GESAMP Hazard Profiles","IMO
IBC Code Chapter 17: Summary of minimum requirements","International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs",
"International Air Transport Association (IATA) Dangerous Goods Regulations","International Air Transport Association (IATA) Dangerous Goods Regulations -
Prohibited List Passenger and Cargo Aircraft","International Council of Chemical Associations (ICCA) - High Production Volume List","International Fragrance
Association (IFRA) Survey: Transparency List","OECD List of High Production Volume (HPV) Chemicals"
2-ethylhexylbenzoate (CAS: 5444-75-7) is found on the following regulatory lists;
"FEMA Generally Recognized as Safe (GRAS) Flavoring Substances 24 - Primary Names and Synonyms","OECD List of High Production Volume (HPV) Chemicals"
dibenzoyl peroxide (CAS: 94-36-0) is found on the following regulatory lists;
"Acros Transport Information","Australia - South Australia Controlled Substances (Poisons) Regulations - Schedule E: Schedule 2 poisons authorised to be sold
by holder of a medicine sellers licence","Australia - Victoria Occupational Health and Safety Regulations - Schedule 9: Materials at Major Hazard Facilities
(And Their Threshold Quantity) Table 2","Australia Australian Pesticides and Veterinary Medicines Authority (APVM) Record of approved active constituents",
"Australia Dangerous Goods Code (ADG Code) - Goods Too Dangerous To Be Transported","Australia Dangerous Goods Code (ADG Code) - List of Currently Assigned
Organic Peroxides in Packagings","Australia Exposure Standards","Australia Hazardous Substances","Australia Inventory of Chemical Substances (AICS)","Australia
Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)","Australia Standard for the Uniform Scheduling of Medicines and
Poisons (SUSMP) - Appendix F (Part 3)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 2","Australia Standard for
the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 4","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) -
Schedule 5","International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs","International Air Transport Association (IATA)
Dangerous Goods Regulations","International Air Transport Association (IATA) Dangerous Goods Regulations - Prohibited List Passenger and Cargo Aircraft",
"International Numbering System for Food Additives","OECD List of High Production Volume (HPV) Chemicals","Sigma-AldrichTransport Information","United Nations
Consolidated List of Products Whose Consumption and/or Sale Have Been Banned, Withdrawn, Severely Restricted or Not Approved by Governments"
No data for Iccons M50E,MC50 Styrene Free Polyester Adhesive Injection (CW: 4795-85)
continued.
ICCONS M50E,MC50 STYRENE FREE POLYESTER ADHESIVE INJECTION
Chemwatch Independent Material Safety Data Sheet
Issue Date: 21-Mar-2013
CHEMWATCH 4795-85
Version No:5.1.1.1
CD 2013/1 Page 14 of 14
Section 16 - OTHER INFORMATION
Denmark Advisory list for selfclassification of dangerous substances
Substance
INGREDIENTS WITH MULTIPLE CAS NUMBERS
Ingredient Name
■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at: www.chemwatch.net/references.
■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review orcriticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH. TEL (+61 3) 9572 4700. Issue Date: 21-Mar-2013Print Date: 21-Mar-2013

Source: http://www.iccons.com.au/msds/1%20-%20M50E%20MC50%20Chemwatch%20%20MSDS%204795-85.pdf