MATERIAL SAFETY DATA SHEET ALSAN TRAFIK HP 510 LO PROTECTIVE CLOTHING TRANSPORT OF DANGEROUS GOODS NOT REGULATED SECTION I: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Waterproofing polyurethane primer single-component.
Formula number: Manufacturer: Soprema Distributors: Soprema 1675 Haggerty Street 44955 Yale Road West 310 Quadral Drive Drummondville (Quebec) J2C 5P7 Chilliwack (B.-C.) V2R 4H3 Wadsworth (Ohio) 44281 Tel.: 819 478-8163 Tel.: 604 793-7100 Tel.: 1 800 356-3521 In case of emergency: SOPREMA (8:00am to 5:00pm): 1 800 567-1492 CANUTEC (Canada) (24h.):613 996-6666 CHEMTREC (USA) (24h.): 1 800 424-9300 EMERGENCY OVERVIEW!!! Caution! Combustible liquid and vapours. The vapours are heavier than air and may spread long distances to a distant ignition source (such as a pilot light, and any object that sparks, such as an electric motor) and flash back. Harmful if inhaled. May cause irritation to eyes, skin and respiratory tract. Harmful or fatal if swallowed. Ingestion of the product can cause severe lung injury when aspirated. May cause cancer. This product contains isocyanates. May cause allergic or asthmatic symptoms or breathing difficulties if inhaled. May cause allergic skin reaction. Irritating and/or toxic gases or fumes may be generated by thermal decomposition or combustion. SECTION II: COMPOSITION AND INFORMATION ON DANGEROUS INGREDIENTS EXPOSURE LIMIT (ACGIH) TLV-STEL Dipropylene glycol methyl ether acetate (DPMA) Diphenylemethane diisocyanate (MDI) [3-(2,3-Epoxypropoxy) propyl] trimethoxysilane Benzoyl Chloride SECTION III: POTENTIAL HEALTH EFFECTS (3-[2,3-Epoxypropoxy] propyl) trimethoxysilane: Vapour generated at
ambient temperature should not cause any harmful health effect at short
Effects of Short-Term (Acute) Exposure
term. Nevertheless this product can form methanol in case of
hydrolysis. Vapours of methanol may cause dizziness, drowsiness,
INHALATION DPMA: No adverse effects are anticipated from single exposure to
visual troubles and also tingling, numbing and lancinating pains to
hands and forearms. This product may cause a sensitization by
MDI: MDI has a very low vapour pressure. Therefore, airborne
exposures are unlikely to occur unless MDI is heated or forms an
SKIN CONTACT
aerosol or mist during pouring, frothing or spraying operations. Short-
DPMA:. DPMA is a non-irritant based on animal information. (1)
term inhalation exposure to isocyanates can cause respiratory and
DPMA:. Prolonged exposure not likely to cause significant skin
mucous membrane irritation. Symptoms include eye and nose irritation,
dry or sore throat, runny nose, shortness of breath, wheezing and
laryngitis. Coughing with chest pain or tightness may also occur,
MDI: MDI can cause moderate irritation. Isocyanates, in general, can
frequently at night. These symptoms may occur during exposure or
cause skin discolouration (staining) and hardening of the skin after
may be delayed several hours. Some people may become sensitized to
repeated exposures. Skin sensitization, resulting in dermatitis, may
MDI (see Effects of Long-term (Chronic) Exposure for information).
occur in some individuals. Skin contact is not expected to result in the
High aerosol concentrations could cause inflammation of the lung
tissue (chemical pneumonitis), chemical bronchitis with severe asthma-
(3-[2,3-Epoxypropoxy] propyl) trimethoxysilane: This product causes
like wheezing, severe coughing spasms and accumulation of fluid in the
a minor irritation. It causes the following effects: local malaise and
lungs (pulmonary oedema), which could prove fatal. Symptoms of
redness. An increase of skin pigmentation can occur. (2)
pulmonary oedema may not appear until several hours after exposure
and are aggravated by physical exertion. (1)
Alsan Trafik HP 510 LO Revision date: November 4, 2009 Page 1 of 5
Benzoyl Chloride: Benzoyl chloride is corrosive to skin based on RESPIRATORY SENSITIZATION
animal information and because it reacts violently with moisture to
MDI: Respiratory sensitization has developed in people working with
produce heat, benzoic acid and hydrogen chloride gas, and with air to
MDI. The sensitization is usually caused by a very large exposure or by
form corrosive fumes. Corrosive materials are capable of producing
multiple exposures. Although varying periods of exposure (1 day to
severe burns, blisters, ulcers and permanent scarring, depending on the
years) may elapse before sensitization occurs, it develops more often
concentration of the solution and the duration of contact. No human
during the first few months of exposure. Sensitized individuals react to
very low levels of MDI (as low as 0.0014 ppm) that have no effect on
unsensitized people. At first, the symptoms may appear to be a cold or
SKIN ABSORPTION
mild hay fever. However, severe asthmatic symptoms can develop and
DPMA: Prolonged skin contact with very large amounts may cause
include wheezing, chest tightness, shortness of breath, difficulty
breathing and/or coughing. Fever, chills, general feelings of discomfort,
(3-[2,3-Epoxypropoxy] propyl) trimethoxysilane: Prolonged and
headache and fatigue can also occur. Symptoms may occur
extended should not cause absorption of potentially harmful amounts of
immediately upon exposure, within an hour or several hours after
exposure or both and/or at night. Typically the asthma improves with
removal from exposure (e.g. weekends and vacations) and returns, in
EYE CONTACT
some cases, in the form of an "acute attack", on renewed exposure.
DPMA:. DPMA is a mild irritant based on animal information. (1)
Sensitized people who continue to work with MDI may develop
DPMA : DPMA may cause slight temporary eye irritation. Corneal
symptoms sooner after each exposure. The number and severity of
symptoms may increase. Following removal from exposure, some
workers may continue to have persistent respiratory problems such as
MDI: Contact with MDI liquid, mist and aerosols may cause slight
asthmatic symptoms, bronchial problems and hypersensitivity to MDI.
irritation with tearing and discomfort. (1)
Others may recover fully and may gradually lose their sensitivity
(3-[2,3-Epoxypropoxy] propyl) trimethoxysilane: This product causes
within several years. MDI may also cause hypersensitivity
a light irritation. It causes the following effects: malaise, pain,
pneumonitis, another allergic lung disease, which is characterized by
excessive blinking of the eyes, watering of the eyes, excessive and
symptoms such as shortness of breath, fever, tiredness, non-productive
m rked redness at the conjunctiva, swelling at the conjunctiva. (2)
cough, and chills. Several studies have shown that continued exposure
to low levels of MDI and other isocyanates may cause impaired lung
Benzoyl Chloride: Benzoyl chloride is corrosive to eyes based on
function, such as diminished respiratory capacity. Other studies have
animal information and because it reacts violently with moisture to
shown that extremely low levels of MDI (e.g. less than 0.003 ppm) do
produce heat, benzoic acid and hydrogen chloride gas, and with air to
not decrease lung function. Cross-sensitization between different
form corrosive fumes. Corrosive materials are capable of producing
isocyanates may occur. People sensitized to toluene diisocyanate (TDI)
severe eye burns, and permanent injury, including blindness, depending
or hexamethylene diisocyanate (HDI) may show sensitization to MDI,
on the concentration of the solutions and duration of contact. No human
aving previous exposure to this chemical. (1)
SKIN SENSITIZATION INGESTION MDI: Allergic contact dermatitis has developed from occupational DPMA: Very low toxicity if swallowed. Harmful effects not
contact with MDI. It has been proposed that a break-down (hydrolysis)
anticipated from swallowing small amounts. (2)
people showed reaction to MDA as well as MDI, while one showed
MDI: There have been no reports of human ingestion of MDI. Animal
studies indicate that the toxic effects of the ingestion of MDI are slight.
CARCINOGENICITY
Ingestion could result in irritation and corrosion of the mouth, throat,
MDI: The risk of cancer associated with exposure to isocyanates has
been examined in 4 human population studies. No strong association or
(3-[2,3-Epoxypropoxy] propyl) trimethoxysilane: This product
consistent pattern has been observed. There is one isolated report of a
hydrolyses in the stomach to form methanol. May cause nauseas,
non-smoking painter who developed lung cancer after being exposed to
abdominal pains, vomiting, headaches, dizziness, shortness of breath,
MDI and TDI for 15 years. He also had a 10-year history of lung
weakness, fatigue, leg cramps, agitation, confusion, and behaviour of
disease thought to be caused by exposure to MDI and TDI. It is not
drunk person, visual troubles, drowsiness, coma and death. There can
possible to draw any conclusions from this case report. The
have a delay of many hours between ingestion of methanol and
International Agency for Research on Cancer (IARC) has determined
appearance of signs and symptoms. The observed effects were partly
there is inadequate evidence for the carcinogenicity of MDI or
caused by the acidosis and partly by cerebral oedema. The visual
polymeric MDI in humans. There is limited evidence for the
effects consist of: a blurred vision, a diplopia, a change in the colour
carcinogenicity of a mixture containing MDI and polymeric MDI in
perception, a restriction of the visual field and a total blindness.
experimental animals. IARC has concluded that this chemical is not
Ingestion of moderate amounts of methanol also produces a metabolic
classifiable as to its carcinogenicity to humans (Group 3). The
acidosis. Appearance of symptoms can occur 48 hours after ingestion.
American Conference of Governmental Industrial Hygienists (ACGIH)
A dose of 60-200 ml of methanol is fatal for most of adults. Ingestion
has not assigned a carcinogenicity designation to this chemical. The US
of amounts as low as 10 ml caused blindness. Massive overdoses can
National Toxicology Program (NTP) has not listed this chemical in its
cause liver, kidney and myocardium injuries. (2)
Effects of Long-Term (Chronic) Exposure Benzoyl Chloride: Small human population studies have shown an
increase in lung cancers in employees with combined exposure to
INHALATION
benzoyl chloride and alpha-chlorinated toluenes. IARC has determined
(3-[2,3-Epoxypropoxy] propyl) trimethoxysilane: Long-term repeated
that there is limited evidence for the combined exposure of
overexposure at concentrations of methanol vapours of 3000 ppm or
alphachlorinated toluenes and benzoyl chloride to humans. There is
more may cause a cumulative effect causing nausea, vomiting,
inadequate evidence for the carcinogenicity of benzoyl chloride to
headaches, buzzing ears, insomnia, trembling, unsteady gait, dizziness,
experimental animals. IARC has concluded that this chemical is
blurred vision and diplopia. Liver and/or kidney injuries can occur.
probably carcinogenic to humans (Group 2A). Combined exposures to
Prolonged overexposure to concentrations of 800 and 1000 ppm can
apha-chlorinated toluenes and benzoyl chloride. ACGIH has designated
cause severe ocular injuries on certain persons. (2)
this chemical as not classifiable as a human carcinogen (A4). NTP has
LUNGS/RESPIRATORY SYSTEM
not listed this chemical in its report on carcinogens. (1)
MDI: Exposure to isocyanates is likely to cause aggravation to TERATOGENICITY, EMBRYOTOXICITY, FETOTOXICITY
individuals with existing respiratory disease, such as chronic bronchitis
MDI: No human or animal information is available. (1) Alsan Trafik HP 510 LO Revision date: November 4, 2009 Page 2 of 5
REPRODUCTIVE TOXICITY FIRE FIGHTING INSTRUCTIONS MDI: No human or animal information is available. (1)
Evacuate area. Wear self-contained breathing apparatus and appropriate
protective clothing in accordance with standards. Approach fire from
MUTAGENICITY
upwind and fight fire from maximum distance or use unmanned hose
MDI: In one case report, MDI caused DNA damage in human white
holders or monitor nozzles. Always stay away from containers because
blood cells after inhalation exposure to 5 to 20 ppb. This report
of the high risk of explosion. Stop leak before attempting to put out the
provides insufficient information for determining the mutagenicity of
fire. If leak cannot be stopped, and if there is no risk to the surrounding
MDI. No other human or animal in vivo studies have been reported.
area, let the fire burn itself out. Move containers from fire area if this
MDI induced chromosome aberrations in cultured human lymphocytes,
can be done without risk. Cool containers with flooding quantities of
with and without metabolic activation. It only marginally increased
sister chromatid exchanges at a high dose, with and without metabolic
EXTINGUISHING MEDIA TOXICOLOGICALLY SYNERGISTIC MATERIALS
2, foam. Use of water spray when fighting
fire may be inefficient because of the low flash point of the product.
MDI: No information was located. (1)
POTENTIAL FOR ACCUMULATION SECTION VI: ACCIDENTAL RELEASE MEASURES MDI: MDI can enter the body by inhalation or ingestion. It is probably RELEASE OR SPILL
metabolized to 4,4’-methylene dianiline, which is metabolized further
Ventilate area. Wear appropriate protective equipment during cleanup.
Eliminate all sources of ignition. Shut off source of leak if you can do it
HEALTH COMMENTS
without risk. Contain the spill. Absorb or cover with dry earth, sand or
MDI: In many reports it is not clear whether pure MDI or polymeric
other non-combustible material and transfer to containers. Sweep or
MDI (PMPPI [polymethylene polyphenyl isocyanate], commonly about
shovel into containers with lids, use clean non-sparking tools (sp.:
50% MDI) was being used. In addition, problems with common
plastic) to collect absorbed material. Cover and remove to appropriate
airborne MDI sampling methods may affect the interpretation of
well ventilated area until disposal. Do not touch or walk through spilled
laboratory and workplace exposure studies. (1)
material. Wash spill area with soap and water. Prevent entry into
waterways, sewers, basements or confined areas. Dispose of material
SECTION IV: FIRST AID MEASURES
according to the local environmental regulations.
SKIN CONTACT SECTION VII: HANDLING AND STORAGE
Remove contaminated clothing. Wash thoroughly with soap and water.
HANDLING
I rritation persists, get medical attention.
This product and its vapours are combustible and toxic. Avoid contact
EYE CONTACT
with eyes, skin and clothing. Do not ingest. Avoid breathing mist,
Flush thoroughly with water for at least 15 minutes. If irritation
vapour or dust. Wash hands thoroughly after handling. Before
handling, it is very important that ventilation controls are operating and
protective equipment requirements are being followed. People working
INHALATION
with this product should be properly trained regarding its hazards and
In case of gas or vapour inhalation, move victim to fresh air. If
its safe use. Eliminate all ignition sources (e.g. sparks, open flames, hot
breathing is difficult, give oxygen. If breathing stops, give respiratory
surfaces). Keep away from heat. Ground transfer containers to avoid
static accumulation. Tightly reseal all partially used containers. Do not
SWALLOWING
Do not induce vomiting. Immediately contact local poison control
centre. Should vomiting occur, be sure to keep the victim’s head below
Store in a cool well-ventilated area out of direct sunlight and away
hips to avoid aspiration of vomit into the lungs. Maintain the victim at
from heat and ignition sources. Keep storage areas clear of combustible
rest and obtain immediate medical attention.
materials. No smoking near storage area. Store away from incompatible
materials. Store the product according to occupational health and safety
SECTION V: FIRE-FIGHTING MEASURES
regulations and fire and building codes. Storage area should be clearly
identified, clear of obstruction and accessible only to trained and
FLAMMABILITY:
authorized personnel. Inspect periodically for damage or leaks. Have
EXPLOSION DATA: Sensitivity to mechanical impact: No
appropriate fire extinguishers and spill clean-up equipment near storage
area. Inspect all containers to make sure they are properly labelled.
FLASH POINT: AUTO-IGNITION TEMPERATURE: Not available SECTION VIII: EXPOSURE CONTROLS / PERSONAL FLAMMABILITY LIMITS IN AIR: (% in volume) Not available PROTECTION FIRE AND EXPLOSION HAZARDS HANDS: Wear gloves made from polyvinyl alcohol (PVA) or nitrile.
This product and its vapours may ignite by heat, sparks or flames.
RESPIRATORY: If the TLV is exceeded, if use is performed in a
Vapours may form explosive mixtures with air. Vapours are heavier
poorly ventilated confined area, use an approved respirator in
than air and may travel a considerable distance to a source of ignition
and flash back to a leak or open container. The product may ignite on
EYES: Wear chemical safety goggles in accordance with standards.
contact with strong oxidizing agents. Do not cut, puncture or weld
OTHERS: Eye bath and safety shower. CONTROL OF VAPOURS: Local exhaust is needed to control COMBUSTION PRODUCTS
vapour and dust level to below recommended limits.
Irritating and/or toxic gases or fumes may be generated by thermal
SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES
decomposition or combustion. Toxic and/or irritating gases or fumes
can emanate from empty containers when submitted to high
PHYSICAL STATE: Liquid
temperatures. Combustion of this product may release: gaseous
ODOUR AND APPEARANCE: Transparent liquid with strong odour
hydrocarbons, hydrogen fluoride, hydrogen chloride, carbon oxides,
ODOUR THRESHOLD: Not
formaldehyde, acetaldehyde, methylglyoxal, nitrogen oxides, hydrogen
VAPOUR DENSITY (air = 1): 6.24
cyanide, silicon oxides, phosgene, hydrochloric acid and other irritating
EVAPORATION RATE (Butyl acetate = 1): Not BOILING POINT (760 mm Hg): Not FREEZING POINT: Not Alsan Trafik HP 510 LO Revision date: November 4, 2009 Page 3 of 5
SPECIFIC GRAVITY (H2O = 1): Benzoyl Chloride: (1) SOLUBILITY IN WATER (20°C): Insoluble VOLATILE ORGANIC COMPOUND (V.O.C.) CONTENT: VISCOSITY:
100 Centipoises (Visco Brookfield, 25°C)
SECTION X: STABILITY AND REACTIVITY EYE IRRITATION DPMA: DPMA (mixed isomers) is a mild irritant. (1) STABILITY: This material is stable at handling and storage
conditions recommended under the Section VII.
MDI: MDI has been reported to cause slight eye irritation in CONDITIONS OF REACTIVITY: Avoid excessive heat. MDI is
readily dimerized and trimerized by heat. Exposed to high
Benzoyl Chloride : Benzoyl chloride is corrosive. Application of 0.1 of
temperatures, this product can emit dangerous decomposition products
benzoyl chloride was corrosive in rabbits. No scoring information was
such as fumes, carbon oxide, nitrogen oxide, trace of hydrocyanic acid,
trace of formaldehyde, trace of hydrochloric acid.
SKIN IRRITATION
INCOMPATIBILITY: Keep away from oxidizing agents and from DPMA: DPMA (mixed isomers) is a non-irritant. (1)
highly acid and basic materials to avoid exothermic reactions.
MDI: Application of 0.5 ml MDI (under a cover for 24 hours) caused Strong oxidizing agents – Reacts violently with fire or explosion risk.
slight (92 to 94% MDI) to moderate irritation (95% MDI) in rabbits. (1)
Water – Reacts non-violently at room temperature with release of heat
to form carbon dioxide and inert material made up of polyureas which
Benzoyl Chloride: Prolonged exposure (24-hour) to benzoyl chloride
could rupture closed containers. Toluenendiamine is formed as an
caused corrosion. Application of 0.5 ml benzoyl chloride, under a cover
intermediate product in the reaction. Above 50°C, the reaction becomes
for 24 hours, was corrosive to the ears of rabbits. No scoring
Amines, alcohols, acids, or bases – May react violently with Effects of Short-Term (Acute) Exposure
generation of heat and flammable compounds.
Metal compounds (e.g. organometallic catalysts, such as organotin INHALATION
compounds) – May polymerize with the generation of heat and
MDI: MDI has a very low vapour pressure and it is difficult to achieve
vapour concentrations necessary for inhalation toxicity testing.
Alkaline metals – The reaction is exothermal and flammable
Therefore, inhalation toxicity studies have focused on the effects of the
aerosol. No significant effects were found when rats were exposed to 2,
Halogens – The reaction is exothermal and flammable compounds can
5 and 15 mg/m³ of MDI aerosol for 6 hours/day, 5 days/week for 2
weeks. The overall effect was a decline in respiratory rate which was
Amides, phenols, mercaptans, urethanes, ureas and surface active
determined to be due mainly to MDI’s action as a pulmonary irritant.
agents (surfactants, e.g. non ionic detergents) – May react vigorously
The RD50 (concentration required to reduce the respiratory rate by
or violently with the generation of heat.
HAZARDOUS DECOMPOSITION PRODUCTS: This product SKIN CONTACT
reacts with water and causes an emanation of carbonic gas which would
(3-[2,3-Epoxypropoxy] propyl) trimethoxysilane: Irritating. Moderate
lead to pressure increasing in closed containers. Peroxides can also
EYE CONTACT HAZARDOUS POLYMERISATION: MDI may undergo (3-[2,3-Epoxypropoxy] propyl) trimethoxysilane: Irritating. Severe
uncontrolled exothermic polymerization upon contact with
incompatible materials, especially strong bases, such as triethylamine
INGESTION
and sodium hydroxide, trialkyl phosphines, potassium acetate, many
MDI: Rats were given daily doses of 4.3 to 5 g/kg for 5 days. The only
metal compounds soluble in organic media, or if heated above 204°C.
effect was a slight enlargement of the spleen in 2 of 5 rats. (1)
The resulting pressure build-up could rupture closed containers.
Effects of Long-Term (Chronic) Exposure STABILITY AND REACTIVITY COMMENTS: Isocyanates are
very reactive compounds and are highly reactive toward a large number
INHALATION
of compounds with active hydrogens, particularly at high temperatures
(3-[2,3-Epoxypropoxy] propyl) trimethoxysilane: In rats, the repeated
exposure to a breathable aerosol of an hydrolysate of this product did
not cause any injury to the respiratory tract and did not show any sign
SECTION XI: TOXICOLOGICAL INFORMATION SKIN SENSITIZATION TOXICOLOGICAL DATA MDI: The sensitizing potency of MDI was investigated using the DPMA: (1)
mouse ear-swelling test (MEST). The dose required to sensitize 50% of
the animals was 0.73 mg/kg. In this test, MDI was less potent than
hexamethylene diisocyanate (HDI) and dicyclohexylmethane
diisocyanate (HMDI), but more sensitizing than toluene diisocyanate
MDI: (1)
(TDI). Cross reactivity was observed between MDI and HDI, HMDI
(3-[2,3-Epoxypropoxy] propyl) trimethoxysilane: Negative results in a
test of mark in human (Human Patch Test). (2)
TERATOGENICITY, EMBRYOTOXICITY, FETOTOXICITY (3-[2,3-Epoxypropoxy] propyl) trimethoxysilane: (2) (3-[2,3-Epoxypropoxy] propyl) trimethoxysilane: In a study of toxicity
on the development during which the product was given by a stomach
tube to rats during the period of organogenesis, the only effect noticed
was a very slight fetotoxicity at 3000 mg/kg/day (ossification reduced
on one side) in presence of maternal toxicity but no embryotoxic or
Alsan Trafik HP 510 LO Revision date: November 4, 2009 Page 4 of 5
teratogenic effect. No effect has been noticed at 500 and 1500
HMIS (USA): NFPA (USA):
MUTAGENICITY Flammability Flammability MDI: It is not possible to conclude that MDI is mutagenic. There are Reactivity (water) Reactivity (water)
no studies available using cultured animal cells. MDI has produced
Protective equipment Specific hazard
mostly negative results in short-term bacteria tests. (1)
SECTION XVI: OTHER INFORMATION (3-[2,3-Epoxypropoxy] propyl) trimethoxysilane: Ester of organosilane
shows to be slightly mutagenic in the following in vitro procedures:
Glossary:
Ames test, test on mouse lymphoma and test of sister chromatid
exchange. It is unlikely that this product presents an important
American Society for Testing and Materials
genotoxic hazard, because there were no local oncogenic reactions
following the repeated chronic application on mouse skin. (2)
Department of Transportation (United States)
CARCINOGENICITY
Environmental Protection Agency (United States)
MDI: There is no animal information on the carcinogenicity of MDI
itself. IARC has determined there is limited evidence for the
LD50/LC50: Less high lethal dose and lethal concentration published
carcinogenicity of a mixture containing monomeric and polymeric MDI
National Fire Protection Association (United States)
Occupational Safety & Health Administration (United
Benzoyl Chloride: Small numbers of skin tumours have been observed
following the skin application of benzoyl chloride to mice. Inhalation
Resource Conservation and Recovery Act (United
exposure has produced no significant increase in tumour incidence in
mice. IARC has concluded that there is inadequate evidence for the
carcinogenicity of benzoyl chloride to experimental animals. (1)
TLV-TWA: Threshold Limit Value – Time-weighted average
Workplace Hazardous Materials Information System
SECTION XII: ECOLOGICAL INFORMATION ENVIRONMENTAL EFFECTS References:
Do not allow product or runoff from fire control to enter storm or
(1) CHEMINFO (2009) Canadian Centre of Occupational Health and
sanitary sewers, lakes, rivers, streams, or public waterways. Block off
drains and ditches. Provincial and federal regulations may require that
environmental and/or other agencies be notified of a spill incident. Spill
area must be cleaned and restored to original condition or to the
Code of MSDS: CA U DRU SS FS 133
satisfaction of authorities. May be harmful to aquatic life.
This MSDS has been prepared by: Michel SECTION XIII: DISPOSAL CONSIDERATIONS For more information: 1-800-567-1492 WASTE DISPOSAL
The Material Safety Data Sheets of SOPREMA Canada are available
This product is listed as hazardous waste. Consult local, state,
provincial or territory authorities to know disposal methods. Also listed
as hazardous waste by the RCRA (USA); waste disposal as to follow
Justification of the update:
EPA regulations. Do not dispose of waste with normal garbage or
This MSDS contains all the information required by ANSI Z-400.1-1998
SECTION XIV: TRANSPORT INFORMATION
standard (United States), by regulation 29 CFR Part 1910.1200 of the Hazard
Communication Standard of OSHA, and is in accordance with standard
CLASSIFICATION (TDG – DOT): Not regulated. IDENTIFICATION NUMBER: Not applicable.
To the best of our knowledge, the information contained herein is accurate. SHIPPING NAME: Not applicable. However, neither the above named supplier nor any of its subsidiaries PACKING GROUP: Not applicable. assumes any liability whatsoever for the accuracy or completeness of the CONTAINERS FOLLOW THE STANDARDS. information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present SECTION XV: REGULATORY INFORMATION unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only WHMIS: Class
B3: Combustible liquid (flash point between
hazards that exist.
Class D2A: Very toxic material causing other effects.
Class D2B: Toxic and infectious material - Other effects –
Toxic (MDI: skin irritation, skin sensitization)
All constituents of this product are included on the Domestic Substances List (DSL – Canada)
TSCA: All constituents of this product are included on the Toxic
Substances Control Act Inventory (TSCA – United States).
Alsan Trafik HP 510 LO Revision date: November 4, 2009 Page 5 of 5
capítulo 8 • Mitos y realidades, dudas y críticasExiste una serie de mitos y conceptos falsos acerca del uso clínico del litio. Éstos no solamente circulan entre los pacientes sino entre muchos profesionales. Actualmente el litio sigue siendo un fárma-co fundamental para el tratamiento de los trastornos bipolares, de la agresividad y de la suicidalidad. En todas las guías o algoritmos d
Research Update TRENDS in Immunology Vol.22 No.8 August 2001the sphingosine kinase pathway. Proc. Natl. Acad. 4 Kwak, B. et al. (2000) Statins as a newlyrecognized type of immunomodulator. Nat. Med. specificity and produce side-effects. 5 Proudfoot, A.E. et al. (2000) The strategy ofblocking the chemokine system to combat disease. 6 Reedquist, K.A. et al. (2000) The small GTPase,