Microsoft word - r5513194.rtf

Bayer Environmental Science SAFETY DATA SHEET according to EC Directive 2001/58/EC COOPEX INSECT POWDER DP0,5 1X4KG BUC GB
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product information
16, rue Jean-Marie Leclair 69009 Lyon France Emergency telephone number +33(0)4.72.85.25.25 Telefax +33(0)4.72.85.27.99 Numéro INRS 2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature
Hazardous components
3. HAZARDS IDENTIFICATION
Risk advice to man and the environment
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 4. FIRST AID MEASURES
General advice
Remove contaminated, soaked clothing immediately and dispose of safely.
Inhalation
Move the patient to fresh air and keep at rest. If symptoms persist, call a physician.
Skin contact
Take off all contaminated clothing immediately. Wash off immediately with soap and plenty of water. After skin contact: Apply Vitamin E cream or simple toilet milks. When symptoms persist or in all cases of doubt seek medical advice. Bayer Environmental Science SAFETY DATA SHEET according to EC Directive 2001/58/EC COOPEX INSECT POWDER DP0,5 1X4KG BUC GB
Eye contact
In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Ingestion
Do not induce vomiting. Wash out mouth with water. Keep at rest. Obtain medical attention.
Notes to Physician

Symptoms
Local:, After skin contact: paresthesia (local)., May cause skin and eye irritation., Inhalation may provoke the following symptoms:, irritation, cough
Symptoms
Systemic:, excitement, gastrointestinal discomfort, tremors, Dizziness, headache, listlessness, nausea and vomiting, epigastric pain, muscular fasciculation of limbs, unconsciousness, convulsions and coma (very high doses). This product/preparation contains a pyrethroid. Must NOT be confused with organophosphorus compounds!
Treatment
Local treatment: Initial treatment should be symptomatic and supportive. After eye contact: Instillation of local anaesthetic drops e.g. 1% Amethocaine Hydrochloride eye drops. Give Analgesics as necessary.
Treatment
Systemic treatment: Endotracheal intubation should be done and gastric lavage performed, followed by administration of charcoal. Monitoring of respiratory and cardiac functions. ECG - monitoring (Electrocardiogram). Check for pulmonary oedema in event of inhalation. Keep airway clear, administer artificial respiration if necessary. Against convulsions: give diazepam. For adults 5-10 mg intravenously as necessary until fully sedated; for children 2.5 mg i.v. There is no specific antidote. Contraindication: atropine. Contraindication: derivatives of adrenaline. Recovery: Spontaneous. 5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
water spray carbon dioxide (CO2) dry powder foam Extinguishing media which must not be used for safety reasons
Product itself is non-combustible; fire extinguishing measures to suit surroundings. Specific hazards during fire fighting
In case of fire the evolution of dangerous gases is possible. Special protective equipment for fire-fighters
In the event of fire and/or explosion do not breathe fumes. Bayer Environmental Science SAFETY DATA SHEET according to EC Directive 2001/58/EC COOPEX INSECT POWDER DP0,5 1X4KG BUC GB
Wear self contained breathing apparatus for fire fighting if necessary. Further information
Remove product from areas of fire, or otherwise cool containers with water in order to avoid pressure being built up due to heat. Whenever possible, contain fire-fighting water by diking area with sand or earth. 6. ACCIDENTAL RELEASE MEASURES
Personal Precautions
Keep people away from and upwind of spill/leak. Avoid dust formation. Avoid contact with spilled product or contaminated surfaces. When dealing with a spillage do not eat, drink or smoke. Environmental Precautions
Do not discharge into the drains/surface water/groundwater. Methods for Cleaning Up
Use approved industrial vacuum cleaner for removal. Transfer collected material to heavy duty plastic drums and keep safe for disposal. Clean contaminated floors and objects thoroughly, observing environmental regulations. Additional Advice
Information regarding safe handling, see section 7. Information regarding personal protective equipment, see section 8. Information regarding waste disposal, see section 13. Check also for any local site procedures. 7. HANDLING AND STORAGE
Handling

Advice on safe handling
No specific precautions required when handling unopened packs/containers; follow relevant manual handling advice. Avoid dust formation. Use only in area provided with appropriate exhaust ventilation. Advice on protection against fire and explosion Requirements for storage areas and containers Keep container tightly closed in a dry and well-ventilated place. Store in a place accessible by authorized persons only. Keep away from heat. Keep away from direct sunlight. Protect against moisture. Keep away from food, drink and animal feedingstuffs. Bayer Environmental Science SAFETY DATA SHEET according to EC Directive 2001/58/EC COOPEX INSECT POWDER DP0,5 1X4KG BUC GB
8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Components with workplace control parameters
Personal protective equipment
Wear respirator conforming to EN149FFP1. Wear CE Marked (or equivalent) nitrile rubber gloves (minimum thickness 0,40 mm). Wash when contaminated. Dispose of when contaminated inside, when perforated or when contamination outside cannot be removed. Wash hands always before eating, drinking, smoking or using the toilet. Chemical resistant goggles must be worn. Light protective clothing, PVC PVC boots When using, do not eat, drink or smoke. Remove soiled clothing immediately. Remove soaked protective clothing immediately. Clean hands and face at work intervals and after work. Work in an adequately ventilated room. 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Safety data
10. STABILITY AND REACTIVITY
Extremes of temperature and direct sunlight. Bayer Environmental Science SAFETY DATA SHEET according to EC Directive 2001/58/EC COOPEX INSECT POWDER DP0,5 1X4KG BUC GB
No hazardous reactions when stored and handled according to prescribed instructions. Stable under normal conditions. 11. TOXICOLOGICAL INFORMATION
LD50 (rat) > 5.000 mg/kg Test conducted with a similar formulation. LC50 (rat) > 2.300 mg/l Exposure time: 4 h Test conducted with a similar formulation. LD50 (rabbit) > 10.000 mg/kg Test conducted with a similar formulation. Slight irritant effect - does not require labelling. (rabbit) Test conducted with a similar formulation. Slight irritant effect - does not require labelling. (rabbit) Test conducted with a similar formulation. non-sensitizing. (guinea pig) Information given is based on data on the components and the toxicology of similar products. Cutaneous sensations may occur, such as burning or stinging on the face and mucosae. However, these sensations cause no lesions and are of a transitory nature (max. 24 hours). 12. ECOLOGICAL INFORMATION
Ecotoxicity effects
LC50 (Guppy (Poecilia reticulata)) 0,0076 mg/l Exposure time: 96 h The value mentioned relates to the active ingredient permethrin. EC50 (Water flea (Daphnia magna)) 0,00017 mg/l Exposure time: 48 h The value mentioned relates to the active ingredient permethrin. EC50 (Selenastrum capricornutum) 0,497 mg/l Exposure time: 96 h The value mentioned relates to the active ingredient permethrin. 13. DISPOSAL CONSIDERATIONS
In accordance with current regulations may be taken to waste disposal site or incineration plant, after consultation with site operator and/or with the responsible authority. Bayer Environmental Science SAFETY DATA SHEET according to EC Directive 2001/58/EC COOPEX INSECT POWDER DP0,5 1X4KG BUC GB
Contaminated packaging
Rince empty containers and dispose of them through the ADIVALOR collection organization or another specific collection system. Smaller packagings (consumer products) can also be disposed of through the cost-free Dual Collection System (Green Dot).
Waste key for the unused product
020108 agrochemical waste containing dangerous substances 14. TRANSPORT INFORMATION
ADR/RID/ADNR
UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. 15. REGULATORY INFORMATION
Classification and labelling in accordance with the EC Directive on dangerous preparations 1999/45/EC as amended. Classification: Hazardous components which must be listed on the label: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Bayer Environmental Science SAFETY DATA SHEET according to EC Directive 2001/58/EC COOPEX INSECT POWDER DP0,5 1X4KG BUC GB
This material and its container must be disposed of in a safe way. Use appropriate container to avoid environmental contamination. To avoid risks to man and the environment, comply with the instructions for use. Contains permethrin. May produce an allergic reaction. WHO-classification: III (Slightly hazardous) Législation des Installations Classées pour la Protection de l'Environnement (Loi du 19/07/76 modifiée et Décret du 07/07/92) Rubrique n° 1172 : Stockage et emploi de substances dangereuses pour l'environnement (très toxiques pour les organismes aquatiques) 16. OTHER INFORMATION
Further information
Text of R phrases mentioned in Section 2: May cause sensitization by skin contact. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The information provided in this safety data sheet has been provided according the requirements from the French modified decree "arrêté du 5 janvier 1993". This sheet complements the technical sheet but does not replace it. The information contained in this sheet is based on knowledge of the product at the date of publication and is given in good faith. Users are further reminded of the possible risks of using a product for purposes other than those for which it was intended. The user is fully responsible for taking all the necessary precautions whilst using the product.The aim of the statutory regulations indicated is to help the user to fulfil his obligations regarding the use of hazardous products. This list should not be considered as exhaustive. It does not exonerate the user from fulfilling other existing legal obligations in addition to those mentioned, relating to the use and storage of the product. This remains solely the responsibility of the user. Changes since the last version are highlighted in the margin. This version replaces all previous versions.

Source: http://www.pestproofhs.co.uk/CoopexInsectPowder.pdf